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(4-Acetyl-phenolato)(subphthalo-cyaninato)boron(III).

ABSTRACT: In the title compound, C(32)H(19)BN(6)O(2), the B atom adopts a BON(3) tetra-hedral coordination geometry. In the crystal, pairs of mol-ecules are associated through aromatic ?-? stacking inter-actions between the concave faces of the boronsubphthalocyanine fragments at a centroid-centroid distance of 3.4951?(19)?Å and a weaker inter-action of the same type between the convex faces of the same group [centroid-centroid separation = 3.5669?(18)?Å] also occurs.

SUBMITTER: Paton AS

PROVIDER: S-EPMC3011621 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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(4-Acetyl-phenolato)(subphthalo-cyaninato)boron(III).

Paton Andrew S AS Lough Alan J AJ Bender Timothy P TP

Acta crystallographica. Section E, Structure reports online 20101120 Pt 12

In the title compound, C(32)H(19)BN(6)O(2), the B atom adopts a BON(3) tetra-hedral coordination geometry. In the crystal, pairs of mol-ecules are associated through aromatic π-π stacking inter-actions between the concave faces of the boronsubphthalocyanine fragments at a centroid-centroid distance of 3.4951 (19) Å and a weaker inter-action of the same type between the convex faces of the same group [centroid-centroid separation = 3.5669 (18) Å] also occurs. ...[more]

PMID: 21589533

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