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(Dimethyl sulfoxide-?O)(2-formyl-phenolato-?O,O')[2-(2-oxidobenzyl-idene-amino)-phenolato-?O,N,O']manganese(III).

ABSTRACT: The O-C(6)H(4)-CH=N-C(6)H(4)-O dianion of the title compound, [Mn(C(13)H(9)NO(2))(C(7)H(5)O(2))(C(2)H(6)OS)], acts as an O,N,O'-chelate to bind to the Mn(III) atom, and the three atoms constitute three points [O-Mn-O = 174.43?(11)°] of an octa-hedron around the metal atom. The azomethine linkage is disordered over two positions in a 0.657?(13):0.343?(13) ratio. The deprotonated salicyldehyde anion acts as an O,O'-chelate; the sixth coordination site is represented by the O atom of the dimethyl sulfoxide mol-ecule. The crystal studied was a non-merohedral twin with a minor twin component of 14.2?(3)%.

SUBMITTER: Raja I

PROVIDER: S-EPMC3120452 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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(Dimethyl sulfoxide-κO)(2-formyl-phenolato-κO,O')[2-(2-oxidobenzyl-idene-amino)-phenolato-κO,N,O']manganese(III).

Raja Inba I Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

The O-C(6)H(4)-CH=N-C(6)H(4)-O dianion of the title compound, [Mn(C(13)H(9)NO(2))(C(7)H(5)O(2))(C(2)H(6)OS)], acts as an O,N,O'-chelate to bind to the Mn(III) atom, and the three atoms constitute three points [O-Mn-O = 174.43 (11)°] of an octa-hedron around the metal atom. The azomethine linkage is disordered over two positions in a 0.657 (13):0.343 (13) ratio. The deprotonated salicyldehyde anion acts as an O,O'-chelate; the sixth coordination site is represented by the O atom of the dimethyl s ...[more]

PMID: 21754583

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