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Bis(2-aminopyridinium) tetra-chloridozincate(II).

ABSTRACT: In the title compound, (C(5)H(7)N(2))(2)[ZnCl(4)], the pyridine N atoms are protonated and the [ZnCl(4)](2-) anions adopt a slightly distorted tetra-hedral configuration. In the crystal, weak N-H?Cl hydrogen bonds link the mol-ecules into layers, while weak ?-? inter-actions [centroid-centroid distance = 4.2758?(18)?Å] also help to stabilize the packing.

SUBMITTER: Cai HL

PROVIDER: S-EPMC3011649 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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Bis(2-aminopyridinium) tetra-chloridozincate(II).

Cai Hong-Ling HL Fu Xue-Qun XQ

Acta crystallographica. Section E, Structure reports online 20101117 Pt 12

In the title compound, (C(5)H(7)N(2))(2)[ZnCl(4)], the pyridine N atoms are protonated and the [ZnCl(4)](2-) anions adopt a slightly distorted tetra-hedral configuration. In the crystal, weak N-H⋯Cl hydrogen bonds link the mol-ecules into layers, while weak π-π inter-actions [centroid-centroid distance = 4.2758 (18) Å] also help to stabilize the packing. ...[more]

PMID: 21589278

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