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Dimethyl-ammonium bis-(4-methyl-morpholin-4-ium) tetra-chloridozincate.

ABSTRACT: The title compound, (C(2)H(8)N)(C(5)H(12)NO)[ZnCl(4)], was synthesized by hydro-thermal reaction of ZnCl(2) with 4-methyl-morpholine in a dimethyl-formamide solution. The asymmetric unit is composed of half a [ZnCl(4)](2-) anion, half a 4-methyl-morpholin-4-ium cation and half a dimethyl-ammonium cation, all located on mirror planes parallel to ac. All the amine H atoms are involved in inter-molecular N-H⋯Cl hydrogen bonds, building up an infinite chain parallel to the c axis.

SUBMITTER: Zhang YW

PROVIDER: S-EPMC3152096 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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Dimethyl-ammonium bis-(4-methyl-morpholin-4-ium) tetra-chloridozincate.

Zhang Yan-Wei YW Wang Yan-Fei YF

Acta crystallographica. Section E, Structure reports online 20110630 Pt 7

The title compound, (C(2)H(8)N)(C(5)H(12)NO)[ZnCl(4)], was synthesized by hydro-thermal reaction of ZnCl(2) with 4-methyl-morpholine in a dimethyl-formamide solution. The asymmetric unit is composed of half a [ZnCl(4)](2-) anion, half a 4-methyl-morpholin-4-ium cation and half a dimethyl-ammonium cation, all located on mirror planes parallel to ac. All the amine H atoms are involved in inter-molecular N-H⋯Cl hydrogen bonds, building up an infinite chain parallel to the c axis. ...[more]

PMID: 21836834

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