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Methyl-(phenyl)-bis-(quinoline-2-carbox-ylato-?N,O)tin(IV) monohydrate.

ABSTRACT: The Sn(IV) atom in each of the two independent mol-ecules in the asymmetric unit of the title compound, [Sn(CH(3))(C(6)H(5))(C(10)H(6)NO(2))(2)]·H(2)O, is N,O-chelated by two quinoline-2-carboxyl-ate ions; the dative Sn-N bonds are significantly longer than the covalent Sn-O bonds. The two O and two N atoms comprise a trapezoid, and the diorganotin skeleton is bent over the longer N-N edge [C-Sn-C = 144.2?(1) and 144.5?(1)° in the two independent mol-ecules]. The uncoordinated water mol-ecules serve to connect the skew-trapezoidal bipyramidal tin-bearing mol-ecules, generating a linear chain motif running along the ac diagonal. The crystal studied was a non-merohedral twin having a minor component of 33.2?(1)%.

SUBMITTER: Vafaee M 

PROVIDER: S-EPMC3051546 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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Methyl-(phenyl)-bis-(quinoline-2-carbox-ylato-κN,O)tin(IV) monohydrate.

Vafaee Marzieh M   Amini Mostafa M MM   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20110112 Pt 2

The Sn(IV) atom in each of the two independent mol-ecules in the asymmetric unit of the title compound, [Sn(CH(3))(C(6)H(5))(C(10)H(6)NO(2))(2)]·H(2)O, is N,O-chelated by two quinoline-2-carboxyl-ate ions; the dative Sn-N bonds are significantly longer than the covalent Sn-O bonds. The two O and two N atoms comprise a trapezoid, and the diorganotin skeleton is bent over the longer N-N edge [C-Sn-C = 144.2 (1) and 144.5 (1)° in the two independent mol-ecules]. The uncoordinated water mol-ecules s  ...[more]

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