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[N-((E)-2-{[2-(Dimethyl-amino)-eth-yl]imino-meth-yl}phen-yl)-N-(2,6-dimethyl-phen-yl)anilinido-?N,N',N'']ethyl-zinc.

ABSTRACT: The title eth-yl-zinc complex, [Zn(C(2)H(5))(C(19)H(24)N(3))], bears a tridentate anilinide-aldimine ligand and features one long Zn-N(amine) bond length, attributable to the crowded environment of the coordinated metal, arising from the dimethyl-phenyl group. The Zn(II) ion adopts a distorted tetra-hedral geometry, the dihedral angle between the two benzene rings being 86.05?(16)°.

SUBMITTER: Issa-Madongo M

PROVIDER: S-EPMC3052042 | biostudies-literature | 2011 Feb

REPOSITORIES: biostudies-literature

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[N-((E)-2-{[2-(Dimethyl-amino)-eth-yl]imino-meth-yl}phen-yl)-N-(2,6-dimethyl-phen-yl)anilinido-κN,N',N'']ethyl-zinc.

Issa-Madongo Mathurin M Mu Ying Y

Acta crystallographica. Section E, Structure reports online 20110223 Pt 3

The title eth-yl-zinc complex, [Zn(C(2)H(5))(C(19)H(24)N(3))], bears a tridentate anilinide-aldimine ligand and features one long Zn-N(amine) bond length, attributable to the crowded environment of the coordinated metal, arising from the dimethyl-phenyl group. The Zn(II) ion adopts a distorted tetra-hedral geometry, the dihedral angle between the two benzene rings being 86.05 (16)°. ...[more]

PMID: 21522288

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