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Bis[dicyclo-hexyl-(phenyl)-phosphane-κP]silver(I) perchlorate dichloro-methane monosolvate.

ABSTRACT: In the title compound, [Ag{P(C(6)H(11))(2)(C(6)H(5))}(2)]ClO(4)·CH(2)Cl(2), the Ag(I) atom in the mononuclear complex cation is coordinated by two P atoms of the phosphane ligands [Ag-P = 2.3993 (4) and 2.4011 (4) Å; P-Ag-P = 177.473 (18)°] and the perchlorate anion acts as the counter-anion. There is an Ag⋯O(perchlorate) inter-action of 2.873 (2) Å, which contributes to the slightly non-linear bond angle about the Ag(I) atom. Weak inter-molecular C-H⋯O hydrogen-bonding inter-actions involving phenyl, cyclo-hexyl and dichloro-methane H-atom donors and perchlorate O-atom acceptors contribute to the stabilization of the crystal structure.

SUBMITTER: Munyaneza A

PROVIDER: S-EPMC3099967 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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Bis[dicyclo-hexyl-(phenyl)-phosphane-κP]silver(I) perchlorate dichloro-methane monosolvate.

Munyaneza Apollinaire A Meijboom Reinout R Omondi Bernard B

Acta crystallographica. Section E, Structure reports online 20110326 Pt 4

In the title compound, [Ag{P(C(6)H(11))(2)(C(6)H(5))}(2)]ClO(4)·CH(2)Cl(2), the Ag(I) atom in the mononuclear complex cation is coordinated by two P atoms of the phosphane ligands [Ag-P = 2.3993 (4) and 2.4011 (4) Å; P-Ag-P = 177.473 (18)°] and the perchlorate anion acts as the counter-anion. There is an Ag⋯O(perchlorate) inter-action of 2.873 (2) Å, which contributes to the slightly non-linear bond angle about the Ag(I) atom. Weak inter-molecular C-H⋯O hydrogen-bonding inter-actions involving p ...[more]

PMID: 21753995

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