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Bis(dicyclo-hexyl-phenyl-phosphine)silver(I) nitrate.

ABSTRACT: The title compound, [Ag(C(18)H(27)P)(2)]NO(3), is a mononuclear salt species in which the Ag atom is coordinated by two phosphine ligands, forming a cation, with the nitrate as the counter-anion, weakly inter-acting with the Ag atom, resulting in Ag?O distances of 2.602?(6) and 2.679?(6)?Å. The cationic silver-phosphine complex has a non-linear geometry in which the P-Ag-P angle is 154.662?(19)°. The Ag-P bond lengths are 2.4303?(6) and 2.4046?(5)?Å.

SUBMITTER: Burgoyne AR

PROVIDER: S-EPMC2979226 | biostudies-literature | 2010 Apr

REPOSITORIES: biostudies-literature

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Bis(dicyclo-hexyl-phenyl-phosphine)silver(I) nitrate.

Burgoyne Andrew R AR Meijboom Reinout R Muller Alfred A Omondi Bernard B

Acta crystallographica. Section E, Structure reports online 20100410 Pt 5

The title compound, [Ag(C(18)H(27)P)(2)]NO(3), is a mononuclear salt species in which the Ag atom is coordinated by two phosphine ligands, forming a cation, with the nitrate as the counter-anion, weakly inter-acting with the Ag atom, resulting in Ag⋯O distances of 2.602 (6) and 2.679 (6) Å. The cationic silver-phosphine complex has a non-linear geometry in which the P-Ag-P angle is 154.662 (19)°. The Ag-P bond lengths are 2.4303 (6) and 2.4046 (5) Å. ...[more]

PMID: 21579003

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