Bis(dicyclo-hexyl-phenyl-phosphine)silver(I) nitrate.

ABSTRACT: The title compound, [Ag(C(18)H(27)P)(2)]NO(3), is a mononuclear salt species in which the Ag atom is coordinated by two phosphine ligands, forming a cation, with the nitrate as the counter-anion, weakly inter-acting with the Ag atom, resulting in Ag?O distances of 2.602?(6) and 2.679?(6)?Å. The cationic silver-phosphine complex has a non-linear geometry in which the P-Ag-P angle is 154.662?(19)°. The Ag-P bond lengths are 2.4303?(6) and 2.4046?(5)?Å.

SUBMITTER: Burgoyne AR 

PROVIDER: S-EPMC2979226 | biostudies-literature | 2010 Apr

REPOSITORIES: biostudies-literature