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(Acetyl-acetonato)dibromido[2,2-diphenyl-hydrazin-1-ido(1-)][2,2-diphenyl-hydrazin-1-ido(2-)]molybdenum(VI).

ABSTRACT: In the title compound, [MoBr(2)(C(12)H(11)N(2))(C(12)H(10)N(2))(C(5)H(7)O(2))], the Mo(VI) atom is six-coordinated in a distorted octa-hedral geometry by two N atoms from the diphenyl-hydrazide(1-) and diphenyl-hydrazide(2-) ligands, two O atoms from a bidentate acetyl-acetonate ligand and two Br(-) ions. The mol-ecules form an inversion dimer via a pair of weak C-H?O hydrogen bonds and a ?-? stacking inter-action with a centroid-centroid distance of 3.7401?(12)?Å. Weak intra-molecular C-H?Br inter-actions and an intra-molecular ?-? stacking inter-action with a centroid-centroid distance of 3.8118?(15)?Å are also observed.

SUBMITTER: Bustos C

PROVIDER: S-EPMC3120344 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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(Acetyl-acetonato)dibromido[2,2-diphenyl-hydrazin-1-ido(1-)][2,2-diphenyl-hydrazin-1-ido(2-)]molybdenum(VI).

Bustos Carlos C Alvarez-Thon Luis L Ibañez Andrés A Sánchez Christian C

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

In the title compound, [MoBr(2)(C(12)H(11)N(2))(C(12)H(10)N(2))(C(5)H(7)O(2))], the Mo(VI) atom is six-coordinated in a distorted octa-hedral geometry by two N atoms from the diphenyl-hydrazide(1-) and diphenyl-hydrazide(2-) ligands, two O atoms from a bidentate acetyl-acetonate ligand and two Br(-) ions. The mol-ecules form an inversion dimer via a pair of weak C-H⋯O hydrogen bonds and a π-π stacking inter-action with a centroid-centroid distance of 3.7401 (12) Å. Weak intra-molecular C-H⋯Br in ...[more]

PMID: 21754584

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