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2,2-Dibenzyl-hydrazin-1-ium chloride.

ABSTRACT: In the title salt, C14H17N2(+)·Cl(-), the central N atom is pyramidal (sum of bond angles = 330.9°) and there is a near orthogonal relationship between the benzene rings [dihedral angle = 89.95?(10)°]. The crystal packing features N-H?Cl hydrogen bonds, which lead to a supra-molecular undulating ribbon along the a axis comprising edge-shared eight-membered {?HNH?Cl}2 synthons. The chains are connected into layers in the ab plane by C-H?? inter-actions.

SUBMITTER: Tayamon S

PROVIDER: S-EPMC3588411 | biostudies-literature | 2013 Mar

REPOSITORIES: biostudies-literature

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2,2-Dibenzyl-hydrazin-1-ium chloride.

Tayamon Shahedeh S Ravoof Thahira Begum S A TB Tahir Mohamed Ibrahim Mohamed MI Crouse Karen A KA Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20130216 Pt 3

In the title salt, C14H17N2(+)·Cl(-), the central N atom is pyramidal (sum of bond angles = 330.9°) and there is a near orthogonal relationship between the benzene rings [dihedral angle = 89.95 (10)°]. The crystal packing features N-H⋯Cl hydrogen bonds, which lead to a supra-molecular undulating ribbon along the a axis comprising edge-shared eight-membered {⋯HNH⋯Cl}2 synthons. The chains are connected into layers in the ab plane by C-H⋯π inter-actions. ...[more]

PMID: 23476568

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