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[?-(Phenyl-ethyn-yl)cyclo-penta-dien-yl](?-tetra-phenyl-cyclo-butadiene)cobalt(I).

ABSTRACT: In the title compound, [Co(C(13)H(9))(C(28)H(20))], the Co atom is sandwiched between cyclo-penta-dienyl and cyclo-butadienyl rings that are inclined at a dihedral angle of 2.6?(3)°. The four phenyl rings are tilted with respect to the cyclo-butadienyl plane so that the C(4)Ph(4) unit constitutes a four-bladed propeller. The phenyl ring of the phenyl-alkyne substituent is inclined to the cyclo-penta-dienyl ring at an angle of 34.92?(18)°. The crystal structure is stabilized solely by C-H?? inter-actions which generate a three-dimensional network.

SUBMITTER: Courtney D

PROVIDER: S-EPMC3120504 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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[η-(Phenyl-ethyn-yl)cyclo-penta-dien-yl](η-tetra-phenyl-cyclo-butadiene)cobalt(I).

Courtney Donagh D Manning Anthony R AR McAdam C John CJ Simpson Jim J

Acta crystallographica. Section E, Structure reports online 20110514 Pt 6

In the title compound, [Co(C(13)H(9))(C(28)H(20))], the Co atom is sandwiched between cyclo-penta-dienyl and cyclo-butadienyl rings that are inclined at a dihedral angle of 2.6 (3)°. The four phenyl rings are tilted with respect to the cyclo-butadienyl plane so that the C(4)Ph(4) unit constitutes a four-bladed propeller. The phenyl ring of the phenyl-alkyne substituent is inclined to the cyclo-penta-dienyl ring at an angle of 34.92 (18)°. The crystal structure is stabilized solely by C-H⋯π inter ...[more]

PMID: 21754635

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