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Bis(nitrato-?O)(3-oxapentane-1,5-diamine-?N,O,N')zinc(II).

ABSTRACT: In the title compound, [Zn(NO(3))(2)(C(4)H(12)N(2)O)], the Zn(II) atom is N,O,N'-chelated by a 3-oxapentane-1,5-diamine ligand and is further coordinated by two nitrate anions in a distorted trigonal-bipyramidal geometry. Inter-molecular N-H?O hydrogen bonding is present in the crystal structure. A short O?O contact of 2.816?(8)?Å is observed between the nitrate anions of adjacent mol-ecules.

SUBMITTER: Jia F

PROVIDER: S-EPMC3120581 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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Bis(nitrato-κO)(3-oxapentane-1,5-diamine-κN,O,N')zinc(II).

Jia Fei F Kou Fan F Liu Bin B Jia Bei-Bei BB Wu Hui-Lu HL

Acta crystallographica. Section E, Structure reports online 20110520 Pt 6

In the title compound, [Zn(NO(3))(2)(C(4)H(12)N(2)O)], the Zn(II) atom is N,O,N'-chelated by a 3-oxapentane-1,5-diamine ligand and is further coordinated by two nitrate anions in a distorted trigonal-bipyramidal geometry. Inter-molecular N-H⋯O hydrogen bonding is present in the crystal structure. A short O⋯O contact of 2.816 (8) Å is observed between the nitrate anions of adjacent mol-ecules. ...[more]

PMID: 21754650

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