Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis(nitrato-?O)(3-oxapentane-1,5-diamine-?N,O,N')zinc(II).

ABSTRACT: In the title compound, [Zn(NO(3))(2)(C(4)H(12)N(2)O)], the Zn(II) atom is N,O,N'-chelated by a 3-oxapentane-1,5-diamine ligand and is further coordinated by two nitrate anions in a distorted trigonal-bipyramidal geometry. Inter-molecular N-H?O hydrogen bonding is present in the crystal structure. A short O?O contact of 2.816?(8)?Å is observed between the nitrate anions of adjacent mol-ecules.

SUBMITTER: Jia F

PROVIDER: S-EPMC3120581 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Bis(nitrato-κO)(3-oxapentane-1,5-diamine-κN,O,N')zinc(II).

Jia Fei F Kou Fan F Liu Bin B Jia Bei-Bei BB Wu Hui-Lu HL

Acta crystallographica. Section E, Structure reports online 20110520 Pt 6

In the title compound, [Zn(NO(3))(2)(C(4)H(12)N(2)O)], the Zn(II) atom is N,O,N'-chelated by a 3-oxapentane-1,5-diamine ligand and is further coordinated by two nitrate anions in a distorted trigonal-bipyramidal geometry. Inter-molecular N-H⋯O hydrogen bonding is present in the crystal structure. A short O⋯O contact of 2.816 (8) Å is observed between the nitrate anions of adjacent mol-ecules. ...[more]

PMID: 21754650

Similar Datasets

Bis(imidazole-?N)bis-(nitrato-?O)zinc(II).

Project description:The title complex, [Zn(NO(3))(2)(C(3)H(4)N(2))(2)], contains a Zn(II) centre with a slightly distorted tetra-hedral coordination environment, involving two N atoms from imidazole ligands and two O atoms from nitrate anions. The imino NH groups participate in inter-molecular N-H?O hydrogen bonds.

| S-EPMC2970476 | biostudies-literature

Bis(2-amino-pyrimidine-κN)aqua-(nitrato-κO)(nitrato-κO,O')zinc(II).

Project description:The water-coordinated Zn atom in the title monoaqua zinc nitrate adduct of 2-amino-pyrimidine, [Zn(NO(3))(2)(C(4)H(5)N(3))(2)(H(2)O)], is bonded to a monodentate nitrate ion and is chelated by the other nitrate ion. The heterocyclic ligands coordinate through ring N-donor sites. The coordination geometry about the Zn(II) atom is a distorted octa-hedron. Intra-molecular N-H⋯O hydrogen bonds occur. In the crystal, adjacent adduct mol-ecules are linked by O-H⋯O, O-H⋯N and N-H⋯O hydrogen bonds into a layer motif parallel to (001).

| S-EPMC2983322 | biostudies-literature

Bis[(2-amino-phen-yl)methanol-κN,O]bis-(nitrato-κO)zinc(II).

Project description:In the title compound, [Zn(NO(3))(2)(C(7)H(9)NO)(2)], the Zn(II) atom, lying on a twofold rotation axis, is six-coordinated in a distorted octa-hedral geometry by two N atoms and two O atoms from two (2-amino-phen-yl)methanol ligands and two O atoms from two monodentate nitrate anions. Inter-molecular N-H⋯O, O-H⋯O and C-H⋯O hydrogen bonds stabilize the crystal structure.

| S-EPMC3007881 | biostudies-literature

trans-Diaqua-bis-(cyclo-hexane-1,2-diamine)-zinc(II) dichloride.

Project description:In the title compound, [Zn(C(6)H(14)N(2))(2)(H(2)O)(2)]Cl(2), the Zn(II) atom resides on a special position with site symmetry 2/m and is octa-hedrally coordinated by four N atoms from two trans 1,2-diamino-cyclo-hexane ligands and two water O atoms. In the crystal, N-H⋯Cl and O-H⋯Cl hydrogen bonds link the mol-ecules into a two-dimensional network parallel to the bc plane.

| S-EPMC3099959 | biostudies-literature

(μ-Ethane-1,2-diamine-κN:N')bis-[bis-(ethane-1,2-diamine-κN,N')zinc(II)] tetra-kis-(perchlorate).

Project description:In the title salt, [Zn(2)(C(2)H(8)N(2))(5)](ClO(4))(4), an ethyl-enediamine mol-ecule bridges two bis-(ethyl-enediamine)-zinc units; the five-coordinate Zn atoms show a trigonal-bipyramidal coordination geometry that is distorted towards square-pyramidal (that of one Zn atom is distorted by 12% and that of the other by 34%). The perchlorate ions are all disordered over two positions in a 1:1 ratio. The cation inter-acts weakly with the anion by N-H⋯O hydrogen bonds, generating a three-dimensional network.

| S-EPMC3009181 | biostudies-literature

trans-Bis(4,7-diphenyl-1,10-phenanthroline-?N,N')bis-(nitrato-?O,O')zinc(II).

Project description:The title compound, [Zn(NO(3))(2)(C(24)H(16)N(2))(2)], is a twofold axially symmetric coordination compound. Given that the Zn-O interactions [2.4926?(15) and 2.6673?(15)?Å] can be considered as weakly bonding and the nitrate ions share the same C(2) axis of the Zn(dpp)(2) fragment (dpp is 4,7-diphenyl-1,10-phenanthroline), these anions belong to the coordination sphere of Zn(2+), leading to a complex with an overall coordination number of 8 for the metal ion.

| S-EPMC3011604 | biostudies-literature

{μ-N,N'-Bis[(E)-4-pyridylmethyl-idene]naphthalene-1,5-diamine}bis-[dichlorido(dimethyl sulfide)platinum(II)].

Project description:The title dinuclear platinum compound, [Pt(2)Cl(4)(C(22)H(16)N(4))(C(2)H(6)S)(2)], with a long bridging bipyridyl-type ligand, is centrosymmetric and the Pt(II) cation shows a slightly distorted square-planar coordination geometry. The Cl ligands are trans to each other, with a Cl-Pt-Cl angle of 178.83 (8)°. The pyridine ring forms a dihedral angle of 48.8 (2)° with the planar PtCl(2)SN unit. Within the mol-ecule, the distance between Pt atoms is 20.262 (5) Å and the N⋯N separation between the terminal pyridyl rings is 16.23 (1)Å.

| S-EPMC2960488 | biostudies-literature

catena-Poly[[bis-(nitrato-?O,O')zinc(II)]-?-4,4'-bis-(pyrazol-1-ylmeth-yl)biphenyl-?N:N].

Project description:In the title compound, [Zn(NO(3))(2)(C(20)H(18)N(4))](n), the Zn(II) atom lies on a crystallographic twofold axis and the coordination geometry can be considered as a slightly distorted tetra-hedron defined by two O atoms from two nitrate groups and two N atoms from two ligand mol-ecules. A distorted octa-hedron may be assumed when two of the symmetry-related nitrate O atoms, with Zn-O distances of 2.528?(2)?Å, are added to the coordination environment. Another twofold axis, passing through the middle of the biphenyl bonds, is observed in the crystal structure. A chain along [101] is built up by the ligands linking the Zn(II) ions.

| S-EPMC2979629 | biostudies-literature

Diaqua-bis-(nitrato-?O)bis-(pyridine-?N)manganese(II).

Project description:The structure of the title manganese complex, [Mn(NO3)2(C5H5N)2(H2O)2], consists of discrete monomeric entities with Mn(2+) ions located on centres of inversion. The metal cation is octahedrally coordinated by a trans-N2O4 donor set with the pyridine N atoms located in the apical positions. Discrete mol-ecules are linked by O-H?O hydrogen bonds into one-dimensional supra-molecular infinite chains along the b and c axes.

| S-EPMC3588364 | biostudies-literature

[μ-N,N,N',N'-Tetra-kis(diphenyl-phosphino-meth-yl)benzene-1,4-diamine-κP,P':P'',P''']bis-[bis-(nitrato-κO)palladium(II)].

Project description:The asymmetric unit of the title complex, [Pd(2)(NO(3))(4)(C(58)H(52)N(2)P(4))], contains one half-mol-ecule, in which the central benzene ring is located on a crystallographic centre of inversion. The Pd atom has a distorted square-planar coordination consisting of two P and two O atoms. In the crystal structure, inter-molecular C-H⋯O inter-actions link the mol-ecules into chains, and π-π contacts between the phenyl rings [centroid-centroid distance = 3.928 (3) Å] may further stabilize the structure.

| S-EPMC2977633 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data