Browse
Submit Data
Databases
API
Help

Dataset Information

8 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

{2-[(Benzylphenyl-phosphanyl-κP)methyl]phenyl-κC}iodidobis(trimethyl-phos-phane)cobalt(II).

ABSTRACT: In the title compound, [Co(C(20)H(18)P)I(C(3)H(9)P)(2)], the Co(II) atom has a distorted square-pyramidal geometry, the base of which is comprised of two trans PMe(3) groups, an I atom, and a C atom of the benzyl group. This benzyl group is tethered to the P atom at the apex of the pyramid, thereby forming a five-membered chelated Co-C-C-C-P ring.

SUBMITTER: Jia J

PROVIDER: S-EPMC3151933 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Chlorido(2-imino-methyl-3-fluoro-phenyl-κC,N)tris-(trimethyl-phos-phane-κP)iron.

Project description:The title compound, [Fe(C(7)H(5)FN)Cl(C(3)H(9)P)(3)], was obtained as a product of the reaction of [Fe(Me(3)P)(4)] with a molar equivalent of (2-chloro-6-fluoro-phen-yl)methanimine in diethyl ether. This compound is sensitive to air, and rapidly decomposes when exposed to air for a few minutes. The Fe atom has an octa-hedral coordination geometry in which the bidentate fluoro-phenyl methanimine ligand forms the equatorial plane with the Cl atom and one of the trimethyl-phosphane ligands. The other two trimethyl-phosphane ligands are located in the axial positions. In the crystal, an N-H⋯Cl hydrogen bond occurs.

| S-EPMC3120623 | biostudies-literature

cis-Dichlorido(3-chloro-2-methyl-imino-phenyl-κC,N)-trans-bis-(trimethyl-phosphine-κP)cobalt(III).

Project description:In the title compound, [CoCl(2)(C(8)H(7)ClN)(C(3)H(9)P)(2)], the Co atom displays an octa-hedral coordination, with two cis Cl atoms perpendicular to two trans trimethyl-phosphine ligands as well as trans to the bidentate 3-chloro-2-methyl-imino-phenyl ligand.

| S-EPMC2915139 | biostudies-literature

rac-cis-Dicarbonyl-chlorido{1-[2-(diphenyl-phosphanyl-κP)benz-yl]-3-(phenyl-κC(1))imidazol-2-yl-idene-κC(2)}ruthenium(II) dichloro-methane monosolvate.

Project description:In the title compound, [Ru(C(28)H(22)N(2)P)Cl(CO)(2)]·CH(2)Cl(2), the Ru(II) atom exhibits a distorted octa-hedral coordination geometry. The N-phenyl group of the ligand has undergone orthometalation; as a result, the tridentate phosphane-functionalized N-heterocyclic carbene ligand is coordinating in a meridional fashion. This complex is of inter-est with respect to transfer hydrogenation catalysis and also provides an example of C-H activation behavior in late transition metal complexes. The dichloro-methane solvent mol-ecule is disordered over two sets of sites with an occupancy ratio of 0.873 (14):0.127 (14).

| S-EPMC3435630 | biostudies-literature

Chlorido[5-meth-oxy-1H-benzimidazole-2(3H)-thione-κS]bis-(tri-phenyl-phos-phane-κP)copper(I) methanol disolvate.

Project description:In the title complex, [CuCl(C8H8N2OS)(C18H15P)2]·2CH3OH, the Cu(I) ion is coordinated by one chloride anion, one S atom from the 5-meth-oxy-1H-benzimidazole-2(3H)-thione ligand and two P atoms from two tri-phenyl-phosphine ligands in a distorted tetra-hedral geometry. One of the N-bound H atoms is involved in an intra-molecular N-H⋯Cl hydrogen bond, while another one inter-acts with the solvent methanol mol-ecule via an N-H⋯O hydrogen bond. Inter-molecular O-H⋯Cl and O-H⋯O hydrogen bonds link two further complex mol-ecules and four solvent mol-ecules into a centrosymmetric structural unit. The short distance of 3.624 (4) Å between the centroids of the five- and the six-membered rings of two benzimidazole fragments indicates the presence of π-π inter-actions.

| S-EPMC3998264 | biostudies-literature

4-Di-phenyl-phosphanyl-8-methyl-1,5-naphthyridine.

Project description:In the title compound, C21H17N2P, the dihedral angles between the 1,5-naphthyridine ring system (r.m.s. deviation = 0.005 Å) and the phenyl rings are 89.18 (8) and 77.39 (8)°. The phenyl rings are almost perpendicular, making a dihedral angle of 88.12 (8)°. The only possible inter-molecular inter-action is a very weak aromatic π-π stacking inter-action [centroid-centroid separation = 3.898 (2) Å].

| S-EPMC3685077 | biostudies-literature

2-Di-phenyl-phosphanyl-1-methyl-1H-benzimidazole.

Project description:In the title compound, C20H18N2P, the P atom is bonded to the two phenyl and imidazole groups, with an average P-C bond length of 1.828 (2) Å. The three C-P-C bond angles have values consistent with a tetra-hedral geometry around the P atom with the fourth site occupied by a H atom. Crystal packing is through van der Waals inter-actions.

| S-EPMC3793838 | biostudies-literature

(μ-Piperazine-1,4-dicarbodithio-ato-κS,S:S,S)bis-[bis-(triphenyl-phos-phane-κP)gold(I)] chloro-form disolvate.

Project description:In the title compound, [Au(2)(C(6)H(8)N(2)S(4))(C(18)H(15)P)(4)]·2CHCl(3), the digold complex resides on a crystallographic inversion center and co-crystallizes with two mol-ecules of chloro-form solvent. The piperazine-1,4-dicarbodithio-ate linker has an almost ideal chair conformation. The geometry about the gold atoms is severely distorted tetra-hedral punctuated by a very acute S-Au-S bite angle.

| S-EPMC3247547 | biostudies-literature

{1,3-Bis[(diphenyl-phosphanyl-?P)-oxy]prop-2-yl-?C}iodido(trimethyl-phosphane)cobalt(II).

Project description:The title compound, [Co(C(27)H(25)O(2)P(2))I(C(3)H(9)P)], was synthesized by the addition of 1-iodo-butane to a solution of the parent cobalt complex {1,3-bis-[(diphenyl-phosphan-yl)-oxy]prop-2-yl}bis-(trimethyl-phosphane)cobalt(II). Two five-membered cobaltocycles with considerable ring bending (sum of inter-nal angles = 516.4 and 517.7°) are formed through two P atoms of the PPh(2) groups and a metallated Csp(3) atom. The Co(II) atom is centered in a trigonal-bipyramidal configuration.

| S-EPMC2979230 | biostudies-literature

2-[(Di-methyl-phenyl-phosphanyl-idene)aza-nium-yl]-5-methyl-benzene-sulfonate benzene monosolvate.

Project description:The title compound, C15H18NO3PS·C6H6, is a rare example of a crystallographically characterized exocyclic phosphiniminium-arene-sulfonate zwitterion, which crystallises as its benzene solvate. The crystal structure shows that the N atom is protonated and that the iminium H atom forms both intra- and inter-molecular hydrogen bonds to the single-bonded sulfonate O atom in an R 2 (2)(4) graph-set motif. The dihedral angle between the aromatic rings in the main molecule is 89.49 (8)°.

| S-EPMC3685103 | biostudies-literature

(?(6)-Benzene)-(benzyl-diphenyl-phos-phane)dichloridoruthenium(II).

Project description:In the title compound, [RuCl(2)(C(6)H(6))(C(19)H(17)P)], the Ru(II) atom has a distorted pseudo-octa-hedral coordination environment with the metrical parameters around the metallic core as Ru-centroid(?(6)-benzene) = 1.6894?(11)?Å, Ru-P = 2.3466?(6), Ru-Cl(avg.) = 2.4127?(7)?Å; Cl-Ru-Cl = 88.07?(2) and Cl-Ru-P = 82.77?(2), 87.65?(2)°. The effective cone angle for the benzyl-diphenyl-phosphane was calculated to be 143°. In the crystal C-H?Cl and C-H?? inter-actions are observed.

| S-EPMC3470126 | biostudies-other

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data