Chlorido[5-meth-oxy-1H-benzimidazole-2(3H)-thione-?S]bis-(tri-phenyl-phos-phane-?P)copper(I) methanol disolvate.

ABSTRACT: In the title complex, [CuCl(C8H8N2OS)(C18H15P)2]·2CH3OH, the Cu(I) ion is coordinated by one chloride anion, one S atom from the 5-meth-oxy-1H-benzimidazole-2(3H)-thione ligand and two P atoms from two tri-phenyl-phosphine ligands in a distorted tetra-hedral geometry. One of the N-bound H atoms is involved in an intra-molecular N-H?Cl hydrogen bond, while another one inter-acts with the solvent methanol mol-ecule via an N-H?O hydrogen bond. Inter-molecular O-H?Cl and O-H?O hydrogen bonds link two further complex mol-ecules and four solvent mol-ecules into a centrosymmetric structural unit. The short distance of 3.624?(4)?Å between the centroids of the five- and the six-membered rings of two benzimidazole fragments indicates the presence of ?-? inter-actions.

SUBMITTER: Meng QX 

PROVIDER: S-EPMC3998264 | biostudies-literature | 2014 Feb

REPOSITORIES: biostudies-literature