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Chlorido(2-imino-methyl-3-fluoro-phenyl-?C,N)tris-(trimethyl-phos-phane-?P)iron.

ABSTRACT: The title compound, [Fe(C(7)H(5)FN)Cl(C(3)H(9)P)(3)], was obtained as a product of the reaction of [Fe(Me(3)P)(4)] with a molar equivalent of (2-chloro-6-fluoro-phen-yl)methanimine in diethyl ether. This compound is sensitive to air, and rapidly decomposes when exposed to air for a few minutes. The Fe atom has an octa-hedral coordination geometry in which the bidentate fluoro-phenyl methanimine ligand forms the equatorial plane with the Cl atom and one of the trimethyl-phosphane ligands. The other two trimethyl-phosphane ligands are located in the axial positions. In the crystal, an N-H?Cl hydrogen bond occurs.

SUBMITTER: Xu X 

PROVIDER: S-EPMC3120623 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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Chlorido(2-imino-methyl-3-fluoro-phenyl-κC,N)tris-(trimethyl-phos-phane-κP)iron.

Xu Xiaofeng X   Li Xiaoyan X  

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

The title compound, [Fe(C(7)H(5)FN)Cl(C(3)H(9)P)(3)], was obtained as a product of the reaction of [Fe(Me(3)P)(4)] with a molar equivalent of (2-chloro-6-fluoro-phen-yl)methanimine in diethyl ether. This compound is sensitive to air, and rapidly decomposes when exposed to air for a few minutes. The Fe atom has an octa-hedral coordination geometry in which the bidentate fluoro-phenyl methanimine ligand forms the equatorial plane with the Cl atom and one of the trimethyl-phosphane ligands. The oth  ...[more]

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