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Tetra-aqua-tetra-kis-(4,4'-bipyridine dioxide-?O)terbium(III) octa-cyanido-molybdate(V).

ABSTRACT: In the title compound, [Tb(C(10)H(8)N(2)O(2))(4)(H(2)O)(4)][Mo(CN)(8)], both metal atoms are eight-coordinated. The Tb(III) atom displays a dodecahedral geometry, while the Mo(V) ion exhibits a distorted square-anti-prismatic geometry. The Tb atoms are located on a special position of site symmetry [Formula: see text], whereas the Mo atoms are located on a twofold rotation axis. The cations are linked by O-H?O hydrogen bonds.

SUBMITTER: Qian SY 

PROVIDER: S-EPMC3152000 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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Tetra-aqua-tetra-kis-(4,4'-bipyridine dioxide-κO)terbium(III) octa-cyanido-molybdate(V).

Qian Su-Yan SY   Yuan Ai-Hua AH  

Acta crystallographica. Section E, Structure reports online 20110604 Pt 7

In the title compound, [Tb(C(10)H(8)N(2)O(2))(4)(H(2)O)(4)][Mo(CN)(8)], both metal atoms are eight-coordinated. The Tb(III) atom displays a dodecahedral geometry, while the Mo(V) ion exhibits a distorted square-anti-prismatic geometry. The Tb atoms are located on a special position of site symmetry [Formula: see text], whereas the Mo atoms are located on a twofold rotation axis. The cations are linked by O-H⋯O hydrogen bonds. ...[more]

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