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Sodium N-bromo-2-chloro-benzene-sulfonamidate sesquihydrate.

ABSTRACT: In the title compound, Na(+)·C(6)H(4)BrClNO(2)S(-)·1.5H(2)O, one water mol-ecule has crystallographically imposed twofold symmetry. The Na(+) cation shows a pseudo-octa-hedral coordination provided by three O atoms of water mol-ecules and three sulfonyl O atoms of different N-bromo-2-chloro-benzene-sulfonamidate anions. The S-N distance of 1.579?(6)?Å is consistent with an S=N double-bond character. The crystal structure is stabilized by O-H?Br, O-H?N and O-H?O hydrogen bonds.

SUBMITTER: Gowda BT

PROVIDER: S-EPMC3152083 | biostudies-other | 2011 Jul

REPOSITORIES: biostudies-other

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Sodium N-bromo-2-chloro-benzene-sulfonamidate sesquihydrate.

Gowda B Thimme BT Foro Sabine S Shakuntala K K

Acta crystallographica. Section E, Structure reports online 20110611 Pt 7

In the title compound, Na(+)·C(6)H(4)BrClNO(2)S(-)·1.5H(2)O, one water mol-ecule has crystallographically imposed twofold symmetry. The Na(+) cation shows a pseudo-octa-hedral coordination provided by three O atoms of water mol-ecules and three sulfonyl O atoms of different N-bromo-2-chloro-benzene-sulfonamidate anions. The S-N distance of 1.579 (6) Å is consistent with an S=N double-bond character. The crystal structure is stabilized by O-H⋯Br, O-H⋯N and O-H⋯O hydrogen bonds. ...[more]

PMID: 21836866

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