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Bis(4-methyl-morpholin-4-ium) tetra-bromidozincate(II).

ABSTRACT: The title compound, (C(5)H(12)NO)(2)[ZnBr(4)], was synthesized by hydro-thermal reaction of ZnBr(2) with 4-methyl-morpholine in a HBr/distilled water solution. Each of the two independent cations exhibits a chair conformation; the anion deviates slightly from an tetrahedral configuration. The Zn-Br distances in the anion are in the range of 2.3996?(9)-2.4247?(9)?Å. All of the amine H atoms are involved in bifurcated inter-molecular N-H?Br hydrogen bonds, building up a trimer.

SUBMITTER: Peng CH

PROVIDER: S-EPMC3212140 | biostudies-other | 2011 Aug

REPOSITORIES: biostudies-other

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Bis(4-methyl-morpholin-4-ium) tetra-bromidozincate(II).

Peng Cong-Hu CH Li Yun-Peng YP

Acta crystallographica. Section E, Structure reports online 20110709 Pt 8

The title compound, (C(5)H(12)NO)(2)[ZnBr(4)], was synthesized by hydro-thermal reaction of ZnBr(2) with 4-methyl-morpholine in a HBr/distilled water solution. Each of the two independent cations exhibits a chair conformation; the anion deviates slightly from an tetrahedral configuration. The Zn-Br distances in the anion are in the range of 2.3996 (9)-2.4247 (9) Å. All of the amine H atoms are involved in bifurcated inter-molecular N-H⋯Br hydrogen bonds, building up a trimer. ...[more]

PMID: 22090842

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