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Bis(morpholin-4-ium) tetra-chlorido-cobalt(II).

ABSTRACT: The title compound, (C(4)H(10)NO)(2)[CoCl(4)], is an ionic compound consisting of two protonated tetra-hydro-1,4-oxazine (morpholine) cations and a [CoCl(4)](2-) dianion. The Co(II) ion is in a tetra-hedral coordination geometry. The cations exhibit chair-shaped conformations. A three-dimensional supra-molecular architecture is formed through N-H?Cl and C-H?Cl hydrogen bonds between the dianions and the cations.

SUBMITTER: Wang WZ

PROVIDER: S-EPMC3254319 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

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Bis(morpholin-4-ium) tetra-chlorido-cobalt(II).

Wang Wen-Zhen WZ Ismayilov Rayyat Huseyn RH Lee Gene-Hsiang GH Wen Yuh-Sheng YS Peng Shie-Ming SM

Acta crystallographica. Section E, Structure reports online 20111214 Pt 1

The title compound, (C(4)H(10)NO)(2)[CoCl(4)], is an ionic compound consisting of two protonated tetra-hydro-1,4-oxazine (morpholine) cations and a [CoCl(4)](2-) dianion. The Co(II) ion is in a tetra-hedral coordination geometry. The cations exhibit chair-shaped conformations. A three-dimensional supra-molecular architecture is formed through N-H⋯Cl and C-H⋯Cl hydrogen bonds between the dianions and the cations. ...[more]

PMID: 22259351

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