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Cationic Pd(II)-catalyzed Fujiwara-Moritani reactions at room temperature in water.

ABSTRACT: Pd(II)-catalyzed Fujiwara-Moritani reactions can be carried out without external acid at room temperature and in water as the only medium. A highly active cationic Pd(II) catalyst, [Pd(MeCN)(4)](BF(4))(2), easily activates aromatic C-H bonds to produce electron-rich cinnamates in good yields.

SUBMITTER: Nishikata T

PROVIDER: S-EPMC3152461 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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Cationic Pd(II)-catalyzed Fujiwara-Moritani reactions at room temperature in water.

Nishikata Takashi T Lipshutz Bruce H BH

Organic letters 20100501 9

Pd(II)-catalyzed Fujiwara-Moritani reactions can be carried out without external acid at room temperature and in water as the only medium. A highly active cationic Pd(II) catalyst, [Pd(MeCN)(4)](BF(4))(2), easily activates aromatic C-H bonds to produce electron-rich cinnamates in good yields. ...[more]

PMID: 20364834

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