Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Chloro-bis-(naphthalen-1-yl)phosphane.

ABSTRACT: In the title compound, C(20)H(14)ClP, the dihedral angle between the naphthyl rings is 81.77?(6)°. The crystal packing suggests weak ?-? stacking inter-actions between the naphthyl rings in adjacent units [minimum ring centroid separation 3.7625?(13)?Å].

SUBMITTER: Foi A

PROVIDER: S-EPMC3200679 | biostudies-literature | 2011 Sep

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Chloro-bis-(naphthalen-1-yl)phosphane.

Foi Ana A Suarez Sebastian A SA Doctorovich Fabio F

Acta crystallographica. Section E, Structure reports online 20110831 Pt 9

In the title compound, C(20)H(14)ClP, the dihedral angle between the naphthyl rings is 81.77 (6)°. The crystal packing suggests weak π-π stacking inter-actions between the naphthyl rings in adjacent units [minimum ring centroid separation 3.7625 (13) Å]. ...[more]

PMID: 22059061

Similar Datasets

Tris(naphthalen-1-yl)phosphane chloro-form hemisolvate.

Project description:The title compound, P(C10H7)3·0.5CHCl3, was isolated after the unsuccessful reaction of KSeCN and tris-(naphthalen-1-yl)phosphane. The solvent mol-ecule is disordered about an inversion center. The effective cone angle of the phosphine is 203°. In the crystal, weak C-H?Cl and C-H?? inter-actions are observed.

| S-EPMC3589056 | biostudies-literature

Bis{1-[(E)-(2-chloro-phen-yl)diazen-yl]naphthalen-2-olato}copper(II).

Project description:The Cu(II) atom in the title compound, [Cu(C16H10ClN2O)2], is located on an inversion center and is tetra-coordinated by two N and two O atoms from two bidentate 1-[(E)-(2-chloro-phen-yl)diazen-yl]naphthalen-2-olate ligands, forming a square-planar complex. In the crystal, mol-ecules are linked via weak C-H?O and C-H?Cl hydrogen bonds, forming chains propagating along [010]. There are also ?-? inter-actions present involving adjacent naphthalene rings [centroid-centroid distance = 3.661?(13)?Å].

| S-EPMC3772433 | biostudies-literature

Dicyclo-hexyl-bis-(naphthalen-1-ylmeth-yl)phospho-nium chloride chloro-form disolvate.

Project description:In the title solvated phosphonium salt, C34H40P(+)·Cl(-)·2CHCl3, the two cyclo-hexyl and two 1-naphthyl-methyl groups at the P atom are in a distorted tetra-hedral arrangement [105.26 (6)-113.35 (6)°]. Both cyclo-hexyl rings adopt a chair conformation. The dihedral angle between the naphthyl ring systems is 74.08 (3)°.

| S-EPMC3588969 | biostudies-literature

(?(6)-Benzene)(carbonato-?(2) O,O')[di-cyclohex-yl(naphthalen-1-ylmeth-yl)phosphane-?P]ruthenium(II) chloro-form tris-olvate.

Project description:The title compound, [Ru(CO3)(?(6)-C6H6){(C6H11)2P(CH2C10H7)}]·3CHCl3, was synthesized by carbonation of [RuCl2(?(6)-C6H6){(C6H11)2P(CH2C10H7)}] with NaHCO3 in methanol at room temperature. The Ru(II) atom is surrounded by a benzene ligand, a chelating carbonate group and a phosphane ligand in a piano-stool configuration. The crystal packing is consolidated by C-H?O and C-H?Cl hydrogen-bonding inter-actions between adjacent metal complexes and between the complexes and the solvent mol-ecules. The asymmetric unit contains one metal complex and three chloro-form solvent mol-ecules of which only one was modelled. The estimated diffraction contributions of the other two strongly disordered chloro-form solvent mol-ecules were substracted from the observed diffraction data using the SQUEEZE procedure in PLATON [Spek (2009 ?). Acta Cryst. D65, 148-155].

| S-EPMC4120604 | biostudies-literature

Bis[2-(morpholinometh-yl)phen-yl]phenyl-phosphane.

Project description:The title compound, C(28)H(33)N(2)O(2)P, contains a penta-coordinated P atom as a result of the weak N→P intra-molecular inter-actions, with three C atoms, two N atoms and the lone pair arranged in a dicapped pseudo-tetra-hedral geometry. The morpholine rings exhibit an almost ideal chair conformation. In the crystal, two weak C-H⋯O hydrogen-bond inter-actions link the mol-ecules in layers stacked along the a axis; there are no further inter-actions between the layers.

| S-EPMC2971958 | biostudies-literature

trans-Chlorido{3-chloro-2-[(1-naphth-yl)imino-meth-yl]phenyl-?C,N}bis-(trimethyl-phosphane)nickel(II).

Project description:The title compound, [Ni(C(17)H(11)ClN)Cl(C(3)H(9)P)(2)], was obtained as a product of the reaction of [Ni(PMe(3))(4)] with a molar equivalent of 2,6-dichloro-N-naphthyl-benzaldehyde-amine in diethyl ether. The ? parameter is 0.3, indicating that the coordination geometry is square-pyramidal. The Ni(II) atom lies in the center of a square pyramidal in which one C, one Cl and two P atoms form the basal plane, with the imine N atom in an apical position. Two P-atom donors are located in trans positions.

| S-EPMC3011379 | biostudies-literature

N-(4-Chloro-phen-yl)-2-(naphthalen-1-yl)acetamide.

Project description:In the title compound, C(18)H(14)ClNO, the naphthalene ring system [maximum deviation = 0.014 (9) Å] forms a dihedral angle of 74.8 (2)° with the benzene ring. In the crystal, mol-ecules are linked via N-H⋯O hydrogen bonds into chains propagating along [010].

| S-EPMC3414919 | biostudies-literature

(Di-tert-butyl-phosphan-yl)bis-(diphenyl-phosphan-yl)phosphane.

Project description:The title phosphane, C(32)H(38)P(4) or (Ph(2)P)(2)P(P(t)Bu(2)), has a P atom that is linked to another three P atoms in a pyramidal configuration; the P-P distances in the range 2.2231?(7)-2.2446?(7)?Å indicate that the P-P bonds are single bonds.

| S-EPMC2961699 | biostudies-literature

1-[(3-Chloro-phen-yl)(morpholin-4-yl)-meth-yl]naphthalen-2-ol.

Project description:In the title compound, C(21)H(20)ClNO(2), the dihedral angle between the naphthyl-ene ring system and the phenyl ring is 77.86 (15)°. The morpholine ring adopts a chair conformation. The hydroxyl group is involved in intra-molecular O-H⋯N hydrogen bonding. A weak inter-molecular C-H⋯π inter-action is present in the crystal structure.

| S-EPMC3151918 | biostudies-literature

N-(3-Chloro-4-fluoro-phen-yl)-2-(naphthalen-1-yl)acetamide.

Project description:In the title compound, C(18)H(13)ClFNO, the dihedral angle between the mean planes of the chloro- and fluoro-substituted benzene ring and the naphthalene ring system is 60.5 (8)°. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds, forming a zigzag chain along [101].

| S-EPMC3151961 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data