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Trans-Chlorido{3-chloro-2-[(1-naphth-yl)imino-meth-yl]phenyl-?C,N}bis-(trimethyl-phosphane)nickel(II).

ABSTRACT: The title compound, [Ni(C(17)H(11)ClN)Cl(C(3)H(9)P)(2)], was obtained as a product of the reaction of [Ni(PMe(3))(4)] with a molar equivalent of 2,6-dichloro-N-naphthyl-benzaldehyde-amine in diethyl ether. The ? parameter is 0.3, indicating that the coordination geometry is square-pyramidal. The Ni(II) atom lies in the center of a square pyramidal in which one C, one Cl and two P atoms form the basal plane, with the imine N atom in an apical position. Two P-atom donors are located in trans positions.

SUBMITTER: Cao R

PROVIDER: S-EPMC3011379 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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trans-Chlorido{3-chloro-2-[(1-naphth-yl)imino-meth-yl]phenyl-κC,N}bis-(trimethyl-phosphane)nickel(II).

Cao Ruixia R Sun Hongjian H

Acta crystallographica. Section E, Structure reports online 20101117 Pt 12

The title compound, [Ni(C(17)H(11)ClN)Cl(C(3)H(9)P)(2)], was obtained as a product of the reaction of [Ni(PMe(3))(4)] with a molar equivalent of 2,6-dichloro-N-naphthyl-benzaldehyde-amine in diethyl ether. The τ parameter is 0.3, indicating that the coordination geometry is square-pyramidal. The Ni(II) atom lies in the center of a square pyramidal in which one C, one Cl and two P atoms form the basal plane, with the imine N atom in an apical position. Two P-atom donors are located in trans posit ...[more]

PMID: 21589273

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