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Catena-Poly[[dichloridozinc(II)]-?-1,4-bis-(3-pyridylmeth-yl)piperazine].

ABSTRACT: In the title compound, [ZnCl(2)(C(16)H(20)N(4))](n), tetra-hedrally coordinated divalent Zn atoms are ligated by two Cl atoms and two N-donor atoms from two 1,4-bis-(3-pyridylmeth-yl)-piperazine (3-bpmp) ligands. The tethering 3-bpmp ligands promote the formation of [ZnCl(2)(3-bpmp)](n) chains situated parallel to (02). These chains aggregate via C-H?Cl inter-actions to form supra-molecular layers, which in turn stack to construct the three-dimensional crystal structure.

SUBMITTER: Hardy AM

PROVIDER: S-EPMC2977589 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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catena-Poly[[dichloridozinc(II)]-μ-1,4-bis-(3-pyridylmeth-yl)piperazine].

Hardy Aaron M AM Laduca Robert L RL

Acta crystallographica. Section E, Structure reports online 20090418 Pt 5

In the title compound, [ZnCl(2)(C(16)H(20)N(4))](n), tetra-hedrally coordinated divalent Zn atoms are ligated by two Cl atoms and two N-donor atoms from two 1,4-bis-(3-pyridylmeth-yl)-piperazine (3-bpmp) ligands. The tethering 3-bpmp ligands promote the formation of [ZnCl(2)(3-bpmp)](n) chains situated parallel to (02). These chains aggregate via C-H⋯Cl inter-actions to form supra-molecular layers, which in turn stack to construct the three-dimensional crystal structure. ...[more]

PMID: 21583775

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