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[1,1'-Bis(dicyclo-hexyl-phosphino)cobalto-cenium-?P,P']chlorido(?-cyclo-penta-dien-yl)ruthenium(II) hexa-fluorido-phosphate.

ABSTRACT: In the title structure, [CoRu(C(5)H(5))(C(17)H(26)P)(2)Cl]PF(6), the Ru(II) atom is bonded to a cyclo-penta-dienyl ring, a Cl atom and two P atoms of the chelating 1,1'-bis-(dicyclo-hexyl-phosphino)cobaltocenium (di-cypc) ligand, leading to a three-legged piano-stool coordination. Part of the PF(6) (-) counter-anion is disordered over two positions, with a site-occupancy ratio of 0.898?(7):0.102?(7). The components are linked by C-H?F and C-H?Cl hydrogen bonds.

SUBMITTER: Hou JG

PROVIDER: S-EPMC2979948 | biostudies-literature | 2010 Jan

REPOSITORIES: biostudies-literature

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[1,1'-Bis(dicyclo-hexyl-phosphino)cobalto-cenium-κP,P']chlorido(η-cyclo-penta-dien-yl)ruthenium(II) hexa-fluorido-phosphate.

Hou Jian-Guo JG

Acta crystallographica. Section E, Structure reports online 20100130 Pt 2

In the title structure, [CoRu(C(5)H(5))(C(17)H(26)P)(2)Cl]PF(6), the Ru(II) atom is bonded to a cyclo-penta-dienyl ring, a Cl atom and two P atoms of the chelating 1,1'-bis-(dicyclo-hexyl-phosphino)cobaltocenium (di-cypc) ligand, leading to a three-legged piano-stool coordination. Part of the PF(6) (-) counter-anion is disordered over two positions, with a site-occupancy ratio of 0.898 (7):0.102 (7). The components are linked by C-H⋯F and C-H⋯Cl hydrogen bonds. ...[more]

PMID: 21579679

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