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2-(2-Pyrid-yl)pyridinium (2,2'-bipyridine-?N,N')tetra-kis-(nitrato-?O,O')bis-muthate(III).

ABSTRACT: The structure of the title compound, (C(10)H(9)N(2))[Bi(NO(3))(4)(C(10)H(8)N(2))], consists of 2-(2-pyrid-yl)pyridinium cations and anions [Bi(NO(3))(4)(C(10)H(8)N(2))](-). The Bi(3+) ion lies on the twofold axis. It is coordinated by two nitro-gen atoms from one 2,2'-bipyridine ligand and eight oxygen atoms from four NO(3) (-) anions. The disordered cation is positioned at the inversion centre. The [Bi(NO(3))(4)(C(10)H(8)N(2))](-) anions and 2-(2-pyrid-yl)pyridinium cations are connected via N-H?O hydrogen bonds into chains. Moreover, these chains are further linked into a two-dimensional layered structure through ?-? stacking inter-actions between bipyridine ligands along the c axis [centroid-centroid distance = 2.868?(4)?Å].

SUBMITTER: Meng ZH

PROVIDER: S-EPMC3201447 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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2-(2-Pyrid-yl)pyridinium (2,2'-bipyridine-κN,N')tetra-kis-(nitrato-κO,O')bis-muthate(III).

Meng Zhao-Hui ZH Zhang Shu-Shen SS

Acta crystallographica. Section E, Structure reports online 20110920 Pt 10

The structure of the title compound, (C(10)H(9)N(2))[Bi(NO(3))(4)(C(10)H(8)N(2))], consists of 2-(2-pyrid-yl)pyridinium cations and anions [Bi(NO(3))(4)(C(10)H(8)N(2))](-). The Bi(3+) ion lies on the twofold axis. It is coordinated by two nitro-gen atoms from one 2,2'-bipyridine ligand and eight oxygen atoms from four NO(3) (-) anions. The disordered cation is positioned at the inversion centre. The [Bi(NO(3))(4)(C(10)H(8)N(2))](-) anions and 2-(2-pyrid-yl)pyridinium cations are connected via N- ...[more]

PMID: 22065819

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