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Dichlorido(4'-ferrocenyl-2,2':6',2''-terpyridine-?N,N',N'')zinc acetonitrile monosolvate.


ABSTRACT: The title complex, [FeZn(C(5)H(5))Cl(2)(C(20)H(14)N(3))]·CH(3)CN, is composed of one Zn(II) atom, one 4'-ferrocenyl-2,2':6',2''-terpyridine (fctpy) ligand, two Cl atoms and one acetonitrile solvent mol-ecule. The Zn(II) atom is five-coordinated in a trigonal-bipyramidal geometry by the tridentate chelating fctpy ligand and two Cl atoms.

SUBMITTER: Tang SP 

PROVIDER: S-EPMC3212113 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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Dichlorido(4'-ferrocenyl-2,2':6',2''-terpyridine-κN,N',N'')zinc acetonitrile monosolvate.

Tang Si-Ping SP   Feng Yong-Lan YL   Kuang Dai-Zhi DZ  

Acta crystallographica. Section E, Structure reports online 20110702 Pt 8


The title complex, [FeZn(C(5)H(5))Cl(2)(C(20)H(14)N(3))]·CH(3)CN, is composed of one Zn(II) atom, one 4'-ferrocenyl-2,2':6',2''-terpyridine (fctpy) ligand, two Cl atoms and one acetonitrile solvent mol-ecule. The Zn(II) atom is five-coordinated in a trigonal-bipyramidal geometry by the tridentate chelating fctpy ligand and two Cl atoms. ...[more]

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