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2-[(E)-(2,4,6-Trichloro-phen-yl)imino-meth-yl]phenol.

ABSTRACT: The title mol-ecule, C(13)H(8)Cl(3)NO, exists in a trans configuration with respect to the C=N bond [1.278?(2)?Å]. The benzene rings form a dihedral angle of 24.64?(11)°. The mol-ecular structure is stabilized by an intra-molecular O-H?N hydrogen bond, which generates an S(6) ring motif. In the crystal, ?-? stacking inter-actions [centroid-centroid distances = 3.6893?(14)?Å] are observed.

SUBMITTER: Fun HK

PROVIDER: S-EPMC3212321 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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2-[(E)-(2,4,6-Trichloro-phen-yl)imino-meth-yl]phenol.

Fun Hoong-Kun HK Quah Ching Kheng CK Viveka S S Madhukumar D J DJ Nagaraja G K GK

Acta crystallographica. Section E, Structure reports online 20110706 Pt 8

The title mol-ecule, C(13)H(8)Cl(3)NO, exists in a trans configuration with respect to the C=N bond [1.278 (2) Å]. The benzene rings form a dihedral angle of 24.64 (11)°. The mol-ecular structure is stabilized by an intra-molecular O-H⋯N hydrogen bond, which generates an S(6) ring motif. In the crystal, π-π stacking inter-actions [centroid-centroid distances = 3.6893 (14) Å] are observed. ...[more]

PMID: 22090978

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