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[1,3-Bis(diphenyl-phosphan-yl)propane-?P,P'](1,10-phenanthroline-?N,N')copper(I) perchlorate.

ABSTRACT: The title compound, [Cu(C(12)H(8)N(2))(C(27)H(26)P(2))]ClO(4), crystallizes with two Cu(I) complex cations and two perchlorate anions in the asymmetric unit. Each Cu(I) cation is four-coordinated by two P atoms of a 1,3-bis-(diphenyl-phosphan-yl)propane mol-ecule and two N atoms of a 1,10-phenanthroline ligand, with a coordination geometry that can be considered as distorted tetra-hedral. The crystal studied was twinned with a twin ratio of 0.786?(2):0.214?(2).

SUBMITTER: Xiao YL

PROVIDER: S-EPMC3238633 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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[1,3-Bis(diphenyl-phosphan-yl)propane-κP,P'](1,10-phenanthroline-κN,N')copper(I) perchlorate.

Xiao Ye-Lan YL Zhou Li-Li LL Gao Sen S Jin Qiong-Hua QH Zhang Cun-Lin CL

Acta crystallographica. Section E, Structure reports online 20111109 Pt 12

The title compound, [Cu(C(12)H(8)N(2))(C(27)H(26)P(2))]ClO(4), crystallizes with two Cu(I) complex cations and two perchlorate anions in the asymmetric unit. Each Cu(I) cation is four-coordinated by two P atoms of a 1,3-bis-(diphenyl-phosphan-yl)propane mol-ecule and two N atoms of a 1,10-phenanthroline ligand, with a coordination geometry that can be considered as distorted tetra-hedral. The crystal studied was twinned with a twin ratio of 0.786 (2):0.214 (2). ...[more]

PMID: 22199524

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