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Tris(N,N-di-methyl-anilinium) tri-?-bromido-bis[tribromido-anti-monate(III)].

ABSTRACT: In the title compound, (C8H12N)3[Sb2Br9], two of the three unique N,N-dimethyanilinium cations exhibit flip-flop disorder with an occupancy ratio of 0.58?(1):0.42?(1). N-H?Br hydrogen bonds link the organic cations and bioctahedral face-sharing anions into a three-dimensional network.

SUBMITTER: Kharrat H

PROVIDER: S-EPMC3772401 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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Tris(N,N-di-methyl-anilinium) tri-μ-bromido-bis[tribromido-anti-monate(III)].

Kharrat Houda H Kamoun Slaheddine S Michaud François F

Acta crystallographica. Section E, Structure reports online 20130608 Pt 7

In the title compound, (C8H12N)3[Sb2Br9], two of the three unique N,N-dimethyanilinium cations exhibit flip-flop disorder with an occupancy ratio of 0.58 (1):0.42 (1). N-H⋯Br hydrogen bonds link the organic cations and bioctahedral face-sharing anions into a three-dimensional network. ...[more]

PMID: 24046544

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