Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Tris(N,N-di-methyl-anilinium) tri-?-bromido-bis[tribromido-anti-monate(III)].

ABSTRACT: In the title compound, (C8H12N)3[Sb2Br9], two of the three unique N,N-dimethyanilinium cations exhibit flip-flop disorder with an occupancy ratio of 0.58?(1):0.42?(1). N-H?Br hydrogen bonds link the organic cations and bioctahedral face-sharing anions into a three-dimensional network.

SUBMITTER: Kharrat H

PROVIDER: S-EPMC3772401 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Tris(N,N-di-methyl-anilinium) tri-μ-bromido-bis[tribromido-anti-monate(III)].

Kharrat Houda H Kamoun Slaheddine S Michaud François F

Acta crystallographica. Section E, Structure reports online 20130608 Pt 7

In the title compound, (C8H12N)3[Sb2Br9], two of the three unique N,N-dimethyanilinium cations exhibit flip-flop disorder with an occupancy ratio of 0.58 (1):0.42 (1). N-H⋯Br hydrogen bonds link the organic cations and bioctahedral face-sharing anions into a three-dimensional network. ...[more]

PMID: 24046544

Similar Datasets

Tris(3-methyl-anilinium) penta-chlorido-anti-monate(III) chloride.

Project description:In the title compound, (C(7)H(10)N)(3)[SbCl(5)]Cl, the Sb(III) cation is coordinated by five Cl(-) anions in a distorted square-pyramidal geometry, in which the longest Sb-Cl distance of 3.0319?(14)?Å indicates a weak coordination bond. In the crystal, the 3-methyl-anilinium cations link with the complex antimonate anions and Cl(-) anions via N-H?Cl hydrogen bonds.

| S-EPMC3238716 | biostudies-literature

Tris(4-methyl-anilinium) penta-chlorido-anti-monate(III) chloride monohydrate.

Project description:The title compound, (C(7)H(10)N)(3)[SbCl(5)]Cl·H(2)O, consists of 4-methyl-anilinium cations, Cl(-) and [SbCl(5)](2-) anions and water mol-ecules. The five Cl atoms bound to Sb [Sb-Cl = 2.4043?(9)-2.6262?(11)?Å] form a square-pyramidal coordination environment. In addition, two [SbCl(5)](2-) anions related by an inversion center are joined by Sb?Cl inter-actions [Sb?Cl = 3.7273?(14)?Å] into an [Sb(2)Cl(10)](4-) dimer with two bridging Cl atoms. The anions, water mol-ecules and ammonium groups of the cations are linked by N-H?Cl, N-H?O and O-H?Cl hydrogen bonds, forming layers parallel to the ac plane. The benzene rings of the 4-methyl-anilinium cations are packed between these layers.

| S-EPMC3343837 | biostudies-other

Tris(N,N-di-methyl-anilinium) hexa-bromido-stannate(IV) bromide.

Project description:In the title compound, (C8H12N)3[SnBr6]Br, the anilinium N atom of one of the three unique cations exhibits flip-flop disorder with an 0.60:0.40 occupancy ratio. In the crystal, N-H⋯Br hydrogen bonds link the N,N-di-methyl-anilinium cations and both Br(-) anions and [SnBr6](2-) dianions into a layered arrangement parallel to (001).

| S-EPMC3684876 | biostudies-literature

Bis(2-methyl-piperidinium) penta-chlorido-anti-monate(III).

Project description:The asymmetric unit of the title compound, (C(6)H(14)N)(2)[SbCl(5)], contains one cation and half of the anion on a special position (specifically, the Sb(III) ion and three chloride anions are situated on a mirror plane). In the [SbCl(5)](2-) unit, the Sb(III) ion is coordinated by five chloride anions [Sb-Cl = 2.3721?(11)-2.6656?(12)?Å] in a distorted square-pyramidal geometry. However, one chloride anion from a neighbouring [SbCl(5)](2-) unit provides a short Sb?Cl contact of 3.3600?(12)?Å and completes the Sb coordination environment up to an elongated octa-hedron. In the crystal, N-H?Cl hydrogen bonds link cations and anions into columns propagating along [100].

| S-EPMC3344392 | biostudies-literature

catena-Poly[bis(1,3-benzo-thia-zol-3-ium) [[di-chlorido-anti-monate(III)]-di-μ-chlorido-μ-oxido-[chlorido-anti-monate(III)]-μ-chlorido]].

Project description:The title compound, {(C7H6NS)2[Sb2Cl6O]} n , contains two benzo-thia-zolidium cations and one tri-μ-chlorido-tri-chlorido-μ-oxido-di-anti-monate(III) anion. The structure of the inorganic cation may be described as as being built up from two polyhedra, i.e. a square-pyramidal SbCl4O and a distorted octa-hedral SbOCl5 unit, sharing a common face (comprising the O atom and two Cl atoms). The two benzo-thia-zole cations are quasi-planar and subtend a dihedral angle of 19.93 (5)°. The crystal packing can be described by alternating (100) layers and [001] chains of the organic cations and inorganic anions connected through an extensive three-dimensional network of N-H⋯Cl, C-H⋯O and C-H⋯Cl hydrogen bonds. This is consolidated by slipped π-π stacking, with centroid-to-centroid distances between the benzo-thia-zole rings of 3.7111 (18)-3.8452 (16) Å. These inter-actions link the mol-ecules within the layers and also link the layers together and reinforce the cohesion of the ionic structure.

| S-EPMC4770971 | biostudies-literature

cis-Bromido(methyl-amine)-bis-(propane-1,3-di-amine)-cobalt(III) dibromide.

Project description:In the title compound, [CoBr(CH5N)(C3H10N2)2]Br2, the cobalt(III) ion has a distorted octa-hedral coordination environment and is surrounded by four N atoms in the equatorial plane, with an additional N atom and the Br atom occupying the axial positions. In the crystal, the complex cation and the two counter anions are linked via N-H⋯Br and C-H⋯Br hydrogen bonds, forming a three-dimensional network.

| S-EPMC3772414 | biostudies-literature

Octa-?3-selenido-penta-kis-(tri-ethyl-phos-phane-?P)(tri-methyl-aceto-nitrile-?N)-octa-hedro-hexa-rhenium(III) bis-(hexa-fluorido-anti-monate) tri-methyl-aceto-nitrile monosolvate.

Project description:The crystal structure of the title compound, [Re6Se8{NCC(CH3)3}(Et3P)5](SbF6)2·NCC(CH3)3, contains a face-capped octa-hedral [Re6(?3-Se)8](2+) cluster core. The pseudo-centrosymmetric [Re6Se8](2+) cluster core is bonded through the Re atoms to five tri-ethyl-phosphane ligands and one tri-methyl-aceto-nitrile ligand. No significant interactions are observed between the cationic cluster, the SbF6 (-) anions and the trimethylacetonitrile solvent molecule.

| S-EPMC4120548 | biostudies-literature

Bis(1-methyl-piperazine-1,4-diium) di-?-bromido-bis-[tetra-bromido-bismuthate(III)] dihydrate.

Project description:In the title hydrated salt, (C5H14N2)2[Bi2Br10]·2H2O, the com-plete [Bi2Br10](4-) biocta-hedron is generated by crystallographic inversion symmetry. The diprotonated piperazine ring adopts a chair conformation, with the methyl group occupying an equatorial position. In the crystal, the tetra-anions and water mol-ecules are linked by O-H?Br and O-H?(Br,Br) hydrogen bonds to generate [100] chains. The chains are crosslinked by N-H?Br, N-H?O and C-H?Br hydrogen bonds originating from the piperazinediium dications, thereby forming a three-dimensional network.

| S-EPMC4051086 | biostudies-other

Di-μ-bromido-bis-[(diethyl ether-κO)(2,4,6-tri-methyl-phen-yl)magnesium]: the mesityl Grignard reagent.

Project description:The crystal structure of the title compound, [Mg2Br2(C9H11)2(C4H10O)2], features a centrosymmetric two-centre magnesium complex with half a mol-ecule in the asymmetric unit. The Mg atom is in a considerably distorted Br2CO coordination. Bond lengths and angles are comparable with already published values. The crystal packing is stabilized by C-H⋯π inter-actions linking the complexes into sheets parallel to (0-11).

| S-EPMC3772445 | biostudies-literature

Bis(4,4'-bipyridinium) di-μ-hydroxido-bis-[dihydroxido(pyridine-2,6-dicarboxyl-ato)anti-monate(III,V)] octa-hydrate.

Project description:The reaction of anti-mony(III) chloride, 4,4'-bipyridine (4,4'-bipy) and pyridine-2,6-dicarboxylic acid (pydcH(2)), in a 1:2:2 molar ratio in an aqueous solution, resulted in the formation of the title centrosymmetric disordered mixed-valence Sb(III)/Sb(V) compound, (C(10)H(9)N(2))(2)[Sb(2)(C(7)H(3)NO(4))(2)(OH)(6)]·8H(2)O or (4,4'-bipyH)(2)[Sb(pydc)(OH)(2)(μ-OH)](2)·8H(2)O. The seven donor atoms of the (pydc)(2-) groups and the hydroxido ligands form a distorted penta-gonal-bipyramidal arrangement around the Sb(III)/Sb(V) centers. C-H⋯π stacking inter-actions between CH groups of the complex dianion and the aromatic rings of the (4,4'-bipyH)(+) cations, with a distance of 2.89 Å, are observed. In the crystal structure, a wide range of noncovalent inter-actions, consisting of O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds [D⋯A ranging from 2.722 (2) to 3.137 (3) Å], ion pairing, π-π stacking [centroid-centroid distance of 3.4363 (13) Å] and C-H⋯π inter-actions, connect the various components into a supra-molecular structure.

| S-EPMC2960308 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data