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Bis(2,2'-bipyridine-?N,N')bis-[3-(3-hy-droxyphenyl)propenoato-?O,O]cadmium.

ABSTRACT: The title compound, [Cd(C(9)H(7)O(3))(2)(C(10)H(8)N(2))(2)], was synthesized under mild hydro-thermal conditions. The structure of the complex mol-ecule consists of four approximately planar fragments: two 3-(3-hy-droxyphenyl)propenoate residues and two 2,2'-bipyridine ligands [largest deviation from the least-squares planes is 0.240?(1)?Å for one of 3-(3-hy-droxy-phenyl)propenoate residues]. The dihedral angles formed by the least-squares planes of the 2,2'-bipyridine ligands and the opposite 3-(3-hy-droxyphenyl)propenoate residues are 22.68?(7) and 26.47?(6)°. The CdN(4)O(4) coordination polyhedron can be described as distorted dodecahedral. Inter-molecular O-H?O hydrogen bonds between carboxyl-ate O atoms and hy-droxy groups lead to the formation of chains along the a-axis direction.

SUBMITTER: Zhang CY

PROVIDER: S-EPMC3238787 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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Bis(2,2'-bipyridine-κN,N')bis-[3-(3-hy-droxyphenyl)propenoato-κO,O]cadmium.

Zhang Chun-Yan CY Wen Yi-Hang YH

Acta crystallographica. Section E, Structure reports online 20111130 Pt 12

The title compound, [Cd(C(9)H(7)O(3))(2)(C(10)H(8)N(2))(2)], was synthesized under mild hydro-thermal conditions. The structure of the complex mol-ecule consists of four approximately planar fragments: two 3-(3-hy-droxyphenyl)propenoate residues and two 2,2'-bipyridine ligands [largest deviation from the least-squares planes is 0.240 (1) Å for one of 3-(3-hy-droxy-phenyl)propenoate residues]. The dihedral angles formed by the least-squares planes of the 2,2'-bipyridine ligands and the opposite 3 ...[more]

PMID: 22199664

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