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Poly[(5,5'-dimethyl-2,2'-bipyridine-?N,N')(?(3)-5-hy-droxy-isophthalato-?O:O,O:O)cadmium].

ABSTRACT: In the title compound, [Cd(C(8)H(4)O(5))(C(12)H(12)N(2))], the Cd(II) cation is coordinated by three 5-hy-droxy-isophthalate anions and one 5,5'-bimethyl-2,2'-bipyridine ligand in a distorted CdO(4)N(2) octa-hedral geometry. The 5-hy-droxy-isophthalate anions bridge the Cd cations, forming a two-dimensional polymeric complex parallel to (100). In the complex, the hy-droxy group is linked to the uncoordinated carb-oxy-O atom via an O-H?O hydrogen bond. Weak C-H?O hydrogen bonds are also present in the crystal structure. One of the methyl groups is disordered over two positions in a 0.536?(11):0.464?(11) ratio.

SUBMITTER: Hu XY

PROVIDER: S-EPMC3201542 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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Poly[(5,5'-dimethyl-2,2'-bipyridine-κN,N')(μ(3)-5-hy-droxy-isophthalato-κO:O,O:O)cadmium].

Hu Xi-Ying XY Zhai Wen-Hang WH Ma Ning N Yang Guang-Rui GR

Acta crystallographica. Section E, Structure reports online 20110914 Pt 10

In the title compound, [Cd(C(8)H(4)O(5))(C(12)H(12)N(2))], the Cd(II) cation is coordinated by three 5-hy-droxy-isophthalate anions and one 5,5'-bimethyl-2,2'-bipyridine ligand in a distorted CdO(4)N(2) octa-hedral geometry. The 5-hy-droxy-isophthalate anions bridge the Cd cations, forming a two-dimensional polymeric complex parallel to (100). In the complex, the hy-droxy group is linked to the uncoordinated carb-oxy-O atom via an O-H⋯O hydrogen bond. Weak C-H⋯O hydrogen bonds are also present i ...[more]

PMID: 22065692

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