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Poly[[?(2)-1,2-bis-(4-pyrid-yl)ethene](?(3)-1,3-phenyl-enediacetato)-cadmium].

ABSTRACT: In the title coordination polymer, [Cd(C(10)H(8)O(4))(C(12)H(10)N(2))](n), two centrosymmetrically related Cd(II) atoms are bridged by two 1,3-phenyl-enediacetate ligands forming a chain along the [100] direction. The distorted penta-gonal-bipyramidal coordination about each metal atom is completed by the N atoms of bridging 1,2-bis-(4-pyrid-yl)ethene ligands, which link these one-dimensional chains into a two-dimensional net extending along the (101) plane.

SUBMITTER: Liu D

PROVIDER: S-EPMC3247523 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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Poly[[μ(2)-1,2-bis-(4-pyrid-yl)ethene](μ(3)-1,3-phenyl-enediacetato)-cadmium].

Liu Dong D

Acta crystallographica. Section E, Structure reports online 20111029 Pt 11

In the title coordination polymer, [Cd(C(10)H(8)O(4))(C(12)H(10)N(2))](n), two centrosymmetrically related Cd(II) atoms are bridged by two 1,3-phenyl-enediacetate ligands forming a chain along the [100] direction. The distorted penta-gonal-bipyramidal coordination about each metal atom is completed by the N atoms of bridging 1,2-bis-(4-pyrid-yl)ethene ligands, which link these one-dimensional chains into a two-dimensional net extending along the (101) plane. ...[more]

PMID: 22219828

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