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(?-Piperazine-1,4-dicarbodithio-ato-?S,S:S,S)bis-[bis-(triphenyl-phos-phane-?P)gold(I)] chloro-form disolvate.

ABSTRACT: In the title compound, [Au(2)(C(6)H(8)N(2)S(4))(C(18)H(15)P)(4)]·2CHCl(3), the digold complex resides on a crystallographic inversion center and co-crystallizes with two mol-ecules of chloro-form solvent. The piperazine-1,4-dicarbodithio-ate linker has an almost ideal chair conformation. The geometry about the gold atoms is severely distorted tetra-hedral punctuated by a very acute S-Au-S bite angle.

SUBMITTER: Guzei IA

PROVIDER: S-EPMC3247547 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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(μ-Piperazine-1,4-dicarbodithio-ato-κS,S:S,S)bis-[bis-(triphenyl-phos-phane-κP)gold(I)] chloro-form disolvate.

Guzei Ilia A IA Spencer Lara C LC Lillywhite Stacy S Darkwa James J

Acta crystallographica. Section E, Structure reports online 20111029 Pt 11

In the title compound, [Au(2)(C(6)H(8)N(2)S(4))(C(18)H(15)P)(4)]·2CHCl(3), the digold complex resides on a crystallographic inversion center and co-crystallizes with two mol-ecules of chloro-form solvent. The piperazine-1,4-dicarbodithio-ate linker has an almost ideal chair conformation. The geometry about the gold atoms is severely distorted tetra-hedral punctuated by a very acute S-Au-S bite angle. ...[more]

PMID: 22219852

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