Unknown

Dataset Information

0

?-1,2-Bis-(diphenyl-phos-phino)-ethane-?P:P'-bis-{[1,2-bis-(diphenyl-phosphino)-ethane-?P,P']bromidocopper(I)} acetone disolvate.

ABSTRACT: In the crystal structure of the title compound, [Cu(2)Br(2)(dppe)(3)]·2CH(3)COCH(3) [dppe is 1,2-bis-(diphenyl-phosphino)-ethane, C(26)H(24)P(2)], the two Cu centers are bridged by a dppe ligand and each metal center carries one chelating dppe unit, with the fourth coordination site available for the Br(-) anion. The mol-ecule is centrosymmetric, with the center of symmetry located between the methyl-ene C atoms of the bridging dppe ligand. The crystal structure is stabilized by intra-molecular C-H?Br hydrogen bonds and inter-molecular ?-? inter-actions, with a centroid-to-centroid distance of 3.2055?(1)?Å.

SUBMITTER: Shi WJ 

PROVIDER: S-EPMC2959431 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

μ-1,2-Bis-(diphenyl-phos-phino)-ethane-κP:P'-bis-{[1,2-bis-(diphenyl-phosphino)-ethane-κP,P']bromidocopper(I)} acetone disolvate.

Shi Wen-Juan WJ  

Acta crystallographica. Section E, Structure reports online 20080927 Pt 10

In the crystal structure of the title compound, [Cu(2)Br(2)(dppe)(3)]·2CH(3)COCH(3) [dppe is 1,2-bis-(diphenyl-phosphino)-ethane, C(26)H(24)P(2)], the two Cu centers are bridged by a dppe ligand and each metal center carries one chelating dppe unit, with the fourth coordination site available for the Br(-) anion. The mol-ecule is centrosymmetric, with the center of symmetry located between the methyl-ene C atoms of the bridging dppe ligand. The crystal structure is stabilized by intra-molecular  ...[more]

Similar Datasets

Unknown [?-1,2-Bis(diphenyl-phosphino)ethane-?P:P']bis-{[1,2-bis-(diphenyl-phosphino)ethane-?P,P']cyanidocopper(I)} methanol disolvate.
| S-EPMC3007356 | biostudies-literature
Unknown Monoclinic modification of 1,2-bis-(diphenyl-seleno-phosphino-yl)ethane.
| S-EPMC2959572 | biostudies-literature
Unknown Bis[?-1,2-bis-(diphenyl-phosphino)methane-?P:P']bis-[(?-ethene)nickel(0)] toluene disolvate.
| S-EPMC2960292 | biostudies-literature
Unknown ?-1,2-Bis(diethyl-phosphino)ethane-?P:P'-bis-{[1,2-bis-(diethyl-phosphino)ethane-?P,P']trichloridonitrosyl-tungsten(II)}.
| S-EPMC2960239 | biostudies-literature
Unknown Bis[?-1,2-bis-(diphenyl-phosphino)ethane-?P:P']digold(I)(Au-Au) bis-(trifluoro-methane-sulfonate) acetonitrile disolvate.
| S-EPMC2977105 | biostudies-other
Unknown 1,2-Bis(diphenyl-phosphino)-1,2-diethyl-hydrazine.
| S-EPMC2979499 | biostudies-literature
Unknown 1,1,2,2-Tetra-kis(dimethyl-amino)-ethane-1,2-diium bis-(tetra-phenyl-borate) acetone disolvate.
| S-EPMC3344502 | biostudies-literature
Unknown Bis[1,2-bis-(diphenyl-phosphino)ethane-?P:P']silver(I) bis-(chloro-difluoro-acetato-?O)(4-chloro-phen-yl)diphenyl-stannate(IV).
| S-EPMC2961517 | biostudies-literature
Unknown [1,2-Bis(dimethyl-phosphino)ethane]carbon-yl(?-cyclo-penta-dien-yl)iron(II) diphenyl-phosphinoylborate.
| S-EPMC2960313 | biostudies-literature
Unknown catena-Poly[[(nitrato-κO,O')silver(I)]-μ-1,2-bis-(diphenyl-phosphino)ethane-κP:P'].
| S-EPMC2961910 | biostudies-literature