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?-1,2-Bis-(diphenyl-phos-phino)-ethane-?P:P'-bis-{[1,2-bis-(diphenyl-phosphino)-ethane-?P,P']bromidocopper(I)} acetone disolvate.


ABSTRACT: In the crystal structure of the title compound, [Cu(2)Br(2)(dppe)(3)]·2CH(3)COCH(3) [dppe is 1,2-bis-(diphenyl-phosphino)-ethane, C(26)H(24)P(2)], the two Cu centers are bridged by a dppe ligand and each metal center carries one chelating dppe unit, with the fourth coordination site available for the Br(-) anion. The mol-ecule is centrosymmetric, with the center of symmetry located between the methyl-ene C atoms of the bridging dppe ligand. The crystal structure is stabilized by intra-molecular C-H?Br hydrogen bonds and inter-molecular ?-? inter-actions, with a centroid-to-centroid distance of 3.2055?(1)?Å.

SUBMITTER: Shi WJ 

PROVIDER: S-EPMC2959431 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

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μ-1,2-Bis-(diphenyl-phos-phino)-ethane-κP:P'-bis-{[1,2-bis-(diphenyl-phosphino)-ethane-κP,P']bromidocopper(I)} acetone disolvate.

Shi Wen-Juan WJ  

Acta crystallographica. Section E, Structure reports online 20080927 Pt 10


In the crystal structure of the title compound, [Cu(2)Br(2)(dppe)(3)]·2CH(3)COCH(3) [dppe is 1,2-bis-(diphenyl-phosphino)-ethane, C(26)H(24)P(2)], the two Cu centers are bridged by a dppe ligand and each metal center carries one chelating dppe unit, with the fourth coordination site available for the Br(-) anion. The mol-ecule is centrosymmetric, with the center of symmetry located between the methyl-ene C atoms of the bridging dppe ligand. The crystal structure is stabilized by intra-molecular  ...[more]

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