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Diaqua-bis-(dimethyl sulfoxide-?O)-disaccharinatocadmium.

ABSTRACT: The title compound, [Cd(C(7)H(4)NO(3)S)(2)(C(2)H(6)OS)(2)(H(2)O)(2)], contains a Cd(2+) cation in an octahedral coordination environment. The metal atom is surrounded by the two different neutral ligands dimethyl sulfoxide (DMSO) and water, each coordin-ating through the O atom. The anionic saccharinate (sac; 1,1,3-trioxo-2,3-dihydro-1?(6),2-benzothia-zol-2-ide) ligand coordin-ates through the N atom. Each of the three similar ligand pairs is in a trans configuration with respect to each other. The Cd atom lies on a crystallographic center of symmetry. The DMSO ligand coordinates through the lone pair of electrons on the O atom, as can be seen from the Cd-O-S bond angle of 123.96?(9)°.

SUBMITTER: Potwana FS

PROVIDER: S-EPMC3247552 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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Diaqua-bis-(dimethyl sulfoxide-κO)-disaccharinatocadmium.

Potwana Fezile S W FS Van Zyl Werner E WE

Acta crystallographica. Section E, Structure reports online 20111029 Pt 11

The title compound, [Cd(C(7)H(4)NO(3)S)(2)(C(2)H(6)OS)(2)(H(2)O)(2)], contains a Cd(2+) cation in an octahedral coordination environment. The metal atom is surrounded by the two different neutral ligands dimethyl sulfoxide (DMSO) and water, each coordin-ating through the O atom. The anionic saccharinate (sac; 1,1,3-trioxo-2,3-dihydro-1λ(6),2-benzothia-zol-2-ide) ligand coordin-ates through the N atom. Each of the three similar ligand pairs is in a trans configuration with respect to each other. ...[more]

PMID: 22219857

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