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Catena-Poly[1-[(2-fluoro-benzyl-idene)amino]-quinolinium [plumbate(II)-tri-?-iodido]].

ABSTRACT: The title complex, {(C(16)H(12)FN(2))[PbI(3)]}(n), consists of 1-[(2-fluoro-benzyl-idene)amino]-quinolinium cations and a polymeric PbI(3) (-) anion formed by face-sharing PbI(6) octa-hedra. These octa-hedra form straight and regular infinite chains along the b axis. In the asymmetric unit, one cation and one anionic [PbI(3)](-) fragment are observed in general positions. Polymeric chains are produced by the glide plane perpendicular to the a axis.

SUBMITTER: Zhao HR 

PROVIDER: S-EPMC3254297 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

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catena-Poly[1-[(2-fluoro-benzyl-idene)amino]-quinolinium [plumbate(II)-tri-μ-iodido]].

Zhao Hai-Rong HR  

Acta crystallographica. Section E, Structure reports online 20111207 Pt 1

The title complex, {(C(16)H(12)FN(2))[PbI(3)]}(n), consists of 1-[(2-fluoro-benzyl-idene)amino]-quinolinium cations and a polymeric PbI(3) (-) anion formed by face-sharing PbI(6) octa-hedra. These octa-hedra form straight and regular infinite chains along the b axis. In the asymmetric unit, one cation and one anionic [PbI(3)](-) fragment are observed in general positions. Polymeric chains are produced by the glide plane perpendicular to the a axis. ...[more]

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