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Tris(ethyl-enediamine)manganese(II) sulfate.

ABSTRACT: In the title compound, [Mn(C(2)H(8)N(2))(3)]SO(4), the metal atom (site symmetry 3.2) is coordinated by six N atoms from three ethyl-enediamine (en) ligands in a slightly distorted octa-hedral geometry. The en ligands are generated from one half-mol-ecule in the asymmetric unit. The O atoms of the sulfate anion (S site symmetry 3.2) are disordered over four orientations in a 0.220?(12):0.210?(13):0.203?(14):0.10?(2) ratio, with one of the O atoms having site symmetry 3. In the crystal, the ions are connected by N-H?O hydrogen bonds, forming a three-dimensional network.

SUBMITTER: Lu J

PROVIDER: S-EPMC2970169 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature

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Tris(ethyl-enediamine)manganese(II) sulfate.

Lu Jing J

Acta crystallographica. Section E, Structure reports online 20090909 Pt 10

In the title compound, [Mn(C(2)H(8)N(2))(3)]SO(4), the metal atom (site symmetry 3.2) is coordinated by six N atoms from three ethyl-enediamine (en) ligands in a slightly distorted octa-hedral geometry. The en ligands are generated from one half-mol-ecule in the asymmetric unit. The O atoms of the sulfate anion (S site symmetry 3.2) are disordered over four orientations in a 0.220 (12):0.210 (13):0.203 (14):0.10 (2) ratio, with one of the O atoms having site symmetry 3. In the crystal, the ions ...[more]

PMID: 21577720

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