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Cis-cis-trans-Bis(acetonitrile-?N)dichloridobis(triphenyl-phosphine-?P)ruthenium(II) acetonitrile disolvate.

ABSTRACT: The title compound, [RuCl(2)(C(2)H(3)N)(2)(C(18)H(15)P)(2)]·2C(2)H(3)N, was obtained upon stirring an acetonitrile/ethanol solution of [RuCl(2)(PPh(3))(3)]. In the crystal structure, each Ru(II) ion is coordinated by two Cl [Ru-Cl = 2.4308?(7) and 2.4139?(7)?Å], two N [Ru-N = 2.016?(2) and 2.003?(2)?Å], and two P [Ru-P = 2.3688?(7) and 2.3887?(7)?Å] atoms in a distorted octa-hedral geometry. Packing inter-actions include typical C-H?? contacts involving phenyl groups as well as weak hydrogen bonds between CH(3)CN methyl H atoms and Cl or solvent CH(3)CN N atoms.

SUBMITTER: Al-Far AM 

PROVIDER: S-EPMC2915117 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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cis-cis-trans-Bis(acetonitrile-κN)dichloridobis(triphenyl-phosphine-κP)ruthenium(II) acetonitrile disolvate.

Al-Far Ahmad M AM   Slaughter Legrande M LM  

Acta crystallographica. Section E, Structure reports online 20071212 Pt 1

The title compound, [RuCl(2)(C(2)H(3)N)(2)(C(18)H(15)P)(2)]·2C(2)H(3)N, was obtained upon stirring an acetonitrile/ethanol solution of [RuCl(2)(PPh(3))(3)]. In the crystal structure, each Ru(II) ion is coordinated by two Cl [Ru-Cl = 2.4308 (7) and 2.4139 (7) Å], two N [Ru-N = 2.016 (2) and 2.003 (2) Å], and two P [Ru-P = 2.3688 (7) and 2.3887 (7) Å] atoms in a distorted octa-hedral geometry. Packing inter-actions include typical C-H⋯π contacts involving phenyl groups as well as weak hydrogen bon  ...[more]

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