Ontology highlight
ABSTRACT:
SUBMITTER: Ha K
PROVIDER: S-EPMC3120370 | biostudies-literature | 2011 Jun
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20110507 Pt 6
The asymmetric unit of the title compound, [Mn(CH(3)CN)(C(8)H(6)N(4))(2)(H(2)O)][Mn(C(8)H(6)N(4))(2)(H(2)O)(2)](ClO(4))(4)·2H(2)O, contains two distinct cationic Mn(II) complexes, four perchlorate anions and two solvent water mol-ecules. In the two complexes, both Mn(II) ions are six-coordinated in a distorted octa-hedral environment, but one Mn ion has a cis-N(5)O coordination geometry defined by four N atoms of the two chelating 2,2'-bipyrimidine (bpym) ligands, one N atom of a coordinating ac ...[more]