Ontology highlight
ABSTRACT:
SUBMITTER: Ventocilla CC
PROVIDER: S-EPMC3336154 | biostudies-literature | 2012 Apr
REPOSITORIES: biostudies-literature
The Journal of organic chemistry 20120316 7
Silver-catalyzed silylene transfer to divinyl ketones provided 2-silyloxy-1,3-dienes with control of stereochemistry and regioselectivity. The products participated in Diels-Alder reactions with electron-deficient alkenes and imines to form six-membered-ring products diastereoselectively. Cycloaddition reactions with alkenes bearing chiral auxiliaries provided access to chiral, nonracemic cyclohexenes. The methodology, therefore, represents a synthesis of diastereomerically and enantiomerically ...[more]