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5-Bromo-4-iodo-2-methyl-aniline.

ABSTRACT: The asymmetric unit of the title compound, C(7)H(7)BrIN, contains two independent mol-ecules, which are linked by weak N-H⋯N hydro-den-bonding inter-actions between the amino groups.

SUBMITTER: Liu YJ

PROVIDER: S-EPMC3343968 | biostudies-literature |

REPOSITORIES: biostudies-literature

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4-Iodo-2-methyl-aniline.

Project description:In the mol-ecule of the title compound, C(7)H(8)IN, the methyl C, I and N atoms lie in the benzene ring plane. In the crystal structure, inter-molecular N-H?N hydrogen bonds link the mol-ecules in a stacked arrangement along the a axis.

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Project description:The title compound, C(13)H(11)BrN(2), a Schiff base obtained from 6-bromo-picolinaldehyde and p-toluidine, has an E configuration about the C=N bond. The dihedral angle between the benzene and pyridine rings is 30.4?(1)°.

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4,6-Di-bromo-N-{3-[(4,6-di-bromo-2,3-di-methyl-phenyl)imino]butan-2-yl-idene}-2,3-di-methyl-aniline.

Project description:The title compound, C20H20Br4N2, is a product of the condensation reaction of 4,6-di-bromo-2,3-di-methyl-aniline and butane-2,3-dione. The mol-ecule has a center of symmetry at the mid-point of the central C-C bond. The dihedral angle between the benzene ring and the 1,4-di-aza-butadiene plane is 78.3?(2)°. Niether hydrogen bonding nor aromatic stacking is observed in the crystal structure.

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Bromidotricarbon-yl[4-iodo-N-(pyridin-2-yl-methyl-idene)aniline-?N,N']rhenium(I).

Project description:In the title compound, [ReBr(C(12)H(9)IN(2))(CO)(3)], the coordination geometry of the Re(I) ion is a distorted fac-ReC(3)BrN(2) octa-hedron, arising from the N,N'-bidentate ligand, a bromide ion and a facial arrangement of three carbonyl ligands. The dihedral angle between the aromatic rings in the 4-iodo-N-(pyridin-2-yl-methyl-idene)aniline ligand is 46.2?(3)°. The bromide ion and its corresponding trans CO mol-ecule are disordered over two sets of sites in a 0.966?(3):0.034?(3) ratio.

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4-Bromo-N-(4-bromo-phen-yl)aniline.

Project description:In the title compound, C(12)H(9)Br(2)N, the dihedral angle between the benzene rings is 47.32?(5)°, whereas the pitch angles, or the angles between the mean plane of each aryl group 'propeller blade' and the plane defined by the aryl bridging C-N-C angle, are 18.1?(2) and 31.7?(2)°. No inter-molecular N-H hydrogen bonding is present in the crystal; however, there is a short inter-molecular Br?Br contact of 3.568?(1)?Å.

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N-[(E)-4-Bromo-benzyl-idene]-3,4-di-methyl-aniline.

Project description:In the title compound, C15H14BrN, the dihedral angle between the benzene rings is 6.4?(2)° and the mol-ecule has an E conformation about the C=N bond. In the crystal, mol-ecules are linked by C-H?? inter-actions, forming two-dimensional networks lying parallel to (001).

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N-[(E)-4-Bromo-benzyl-idene]-2,3-di-methyl-aniline.

Project description:The title compound, C15H14BrN, has an E conformation about the C=N bond and the dihedral angle between the benzene rings is 50.7?(2)°. In the crystal, mol-ecules are linked via C-H?? inter-actions, forming columns propagating along [010].

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