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5-Bromo-4-iodo-2-methyl-aniline.

ABSTRACT: The asymmetric unit of the title compound, C(7)H(7)BrIN, contains two independent mol-ecules, which are linked by weak N-H⋯N hydro-den-bonding inter-actions between the amino groups.

SUBMITTER: Liu YJ

PROVIDER: S-EPMC3343968 | biostudies-literature |

REPOSITORIES: biostudies-literature

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4-Iodo-2-methyl-aniline.

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Project description:In the title compound, C7H7Br2N, the C-C-C bond angles of the benzene ring are notably distorted and two short intamolecular N-H⋯Br contacts occur. In the crystal, the mol-ecules are linked by N-H⋯N hydrogen bonds to generate C(2) chains propagating in the [100] direction.

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Project description:The title compound, C(18)H(18)Br(2)N(2), is centrosymmetric with the mid-point of the central C-C bond of the butyl group located on an inversion center. The terminal benzene ring is approximately perpendicular to the central butyl plane [dihedral angle = 71.9?(8)°]. No hydrogen bonding or aromatic stacking is observed in the crystal.

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Project description:The title compound, C20H20Br4N2, is a product of the condensation reaction of 4,6-di-bromo-2,3-di-methyl-aniline and butane-2,3-dione. The mol-ecule has a center of symmetry at the mid-point of the central C-C bond. The dihedral angle between the benzene ring and the 1,4-di-aza-butadiene plane is 78.3?(2)°. Niether hydrogen bonding nor aromatic stacking is observed in the crystal structure.

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Project description:In the title compound, [ReBr(C(12)H(9)IN(2))(CO)(3)], the coordination geometry of the Re(I) ion is a distorted fac-ReC(3)BrN(2) octa-hedron, arising from the N,N'-bidentate ligand, a bromide ion and a facial arrangement of three carbonyl ligands. The dihedral angle between the aromatic rings in the 4-iodo-N-(pyridin-2-yl-methyl-idene)aniline ligand is 46.2 (3)°. The bromide ion and its corresponding trans CO mol-ecule are disordered over two sets of sites in a 0.966 (3):0.034 (3) ratio.

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4-Bromo-N-(4-bromo-phen-yl)aniline.

Project description:In the title compound, C(12)H(9)Br(2)N, the dihedral angle between the benzene rings is 47.32?(5)°, whereas the pitch angles, or the angles between the mean plane of each aryl group 'propeller blade' and the plane defined by the aryl bridging C-N-C angle, are 18.1?(2) and 31.7?(2)°. No inter-molecular N-H hydrogen bonding is present in the crystal; however, there is a short inter-molecular Br?Br contact of 3.568?(1)?Å.

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Project description:The title compound, C(6)H(5)BrClN, is almost planar (r.m.s. deviation = 0.018?Å). In the crystal, mol-ecules are linked by inter-molecular N-H?N and weak N-H?Br hydrogen bonds, generating sheets.

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