Browse
Submit Data
Databases
API
Help

Dataset Information

10 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(R)-N-(Biphenyl-4-yl)-tert-butane-sulfinamide.

ABSTRACT: In the title compound, C(16)H(19)NOS, the dihedral angle between the two aromatic rings is 38.98?(8)°. The crystal structure is stabilized by N-H?O hydrogen bonds, which link neighbouring mol-ecules into chains running parallel to the a axis.

SUBMITTER: Zhang B

PROVIDER: S-EPMC3344516 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

(R)-N-(Biphenyl-4-yl)-tert-butane-sulfinamide.

Zhang Binbin B Wang Yan Y Sun Xiaofei X Wang Wenguo W Zeng Qingle Q

Acta crystallographica. Section E, Structure reports online 20120413 Pt 5

In the title compound, C(16)H(19)NOS, the dihedral angle between the two aromatic rings is 38.98 (8)°. The crystal structure is stabilized by N-H⋯O hydrogen bonds, which link neighbouring mol-ecules into chains running parallel to the a axis. ...[more]

PMID: 22590278

Similar Datasets

N-(4-Methoxy-phen-yl)-tert-butane-sulfinamide.

Project description:In the title compound, C(11)H(17)NO(2)S, the mol-ecules inter-act head-to-tail through N-H?OS hydrogen bonds, giving discrete centrosymmetric cyclic dimers. The N-C(ar-yl) bond length [1.4225?(14)?Å] is inter-mediate between that in N-phenyl-tert-butane-sulfinamide [1.4083?(12)?Å] and the N-C(alk-yl) bond lengths in N-alkyl-alkanesulfinamides (1.470-1.530?Å), suggesting weaker delocalization of electrons over the N atom and the aromatic ring due to the presence of the 4-meth-oxy group.

| S-EPMC2971111 | biostudies-literature

N-Phenyl-tert-butane-sulfinamide.

Project description:In the racemic title compound, C(10)H(15)NOS, the packing exhibits centrosymmetric pairs of mol-ecules linked by N-H?O=S hydrogen bonds in a head-to-tail fashion. The N-C(ar-yl) bond [1.4083?(12)?Å] is considerably shorter than the N-C(alk-yl) bonds typically found in N-alkyl-alkanesulfinamides (1.470-1.530?Å).

| S-EPMC2977387 | biostudies-literature

(S)-N-Phenyl-tert-butane-sulfinamide.

Project description:The asymmetric unit of the title compound, C(10)H(15)NOS, contains two independent mol-ecules with similar conformations. In the crystal, mol-ecules are linked in a head-to-tail fashion by N-H?O hydrogen bonds into chains running along the b axis. The absolute configuration was assigned on the basis of known chirality of the parent compound.

| S-EPMC3379318 | biostudies-literature

N-(3-Methoxy-phen-yl)-tert-butane-sulfinamide.

Project description:In the title compound, C(11)H(17)NO(2)S, the mol-ecules inter-act in a head-to-tail fashion through pairs of N-H?O hydrogen bonds, giving discrete centrosymmetric dimers. The N(H)S(O)(t)Bu fragment is disordered over two sets of positions, with the major component comprising 90.0?(2)%.

| S-EPMC2980236 | biostudies-other

(R)-N-(3-Meth-oxy-phen-yl)-tert-butane-sulfinamide.

Project description:The title compound, C(11)H(17)NO(2)S, was obtained by the reaction of (R)-tert-butane-sulfinamide with 3-meth-oxy-phenyl bromide in toluene. In the crystal, mol-ecules inter-act head-to-tail through N-H?O and C-H?O hydrogen bonds, forming one-dimensional chains parallel to the a axis.

| S-EPMC3297844 | biostudies-other

1,2-Di-tert-butyl-ethane-1,2-diyl bis-(tert-butane-sulfinamide).

Project description:In the title compound, C(18)H(40)N(2)O(2)S(2), a vicinal diamine derivative, the crystal structure is stabilized by two intra-molecular N-H?O hydrogen bonds. The distance between the two kernel chiral C atoms is 1.580?(2)?Å.

| S-EPMC2968083 | biostudies-other

2,3-Bis[(3-methyl-biphenyl-4-yl)imino]-butane.

Project description:The title compound, C30H28N2, is a product of the condensation reaction of 2-methyl-4-phenyl-aniline and butane-2,3-dione. The mol-ecule lies on a crystallographic inversion centre. The C=N bond has an E conformation. The dihedral angle between the two benzene rings of the 4-phenyl-2-methyl-phenyl group is 29.19?(76)°. The 1,4-di-aza-butadiene plane makes an angle of 70.1?(10)° with the N-bonded methyl-phenyl ring and an angle of 81.08?(97)° with the terminal phenyl group.

| S-EPMC3998529 | biostudies-literature

Bis{(R)-N-[(R)-2-benz-yloxy-1-(4-tert-butyl-phen-yl)eth-yl]-2-methyl-propane-2-sulfinamide} monohydrate.

Project description:The asymmetric unit of the title compound, 2C23H33NO2S·H2O, contains one organic mol-ecule in a general position and one co-crystallized water mol-ecule on a crystallographic twofold axis. Each water mol-ecule serves as a hydrogen-bond donor to a pair of S=O acceptors on symmetry-related mol-ecules. Thus, each trio of mol-ecules forms one title formula unit. These groupings are further connected along [010] via weak non-classical C-H?O hydrogen bonds.

| S-EPMC3998603 | biostudies-literature

(Biphenyl-2,2'-di-yl)di-tert-butyl-phos-phonium trifluoro-methane-sulfonate.

Project description:To aid in the elucidation of catalytic reaction mechanism of palladacycles, we found that reaction of trifluoro-methane-sulfonic acid with a phosphapalladacycle resulted in elimination of the palladium and formation of the title phospholium salt, C20H26P(+)·CF3SO3(-). Selected geometrical parameters include P-biphenyl (av.) = 1.801?(3)?Å and P-t-Bu (av.) = 1.858?(3)?Å, and significant distortion of the tetra-hedral P-atom environment with biphen-yl-P-biphenyl = 93.93?(13)° and t-Bu-P-t-Bu = 118.82?(14)°. In the crystal, weak C-H?O inter-actions lead to channels along the c axis that are occupied by CF3SO3(-) anions.

| S-EPMC3588282 | biostudies-literature

(R)-N-{2-tert-Butyl-2-[(R)-tert-butyl-sulfonamido]ethylidene}-tert-butane-sulfonamide.

Project description:The title compound, C(14)H(30)N(2)O(2)S(2), is the product of the monoaddition reaction of tert-butyl magnesium chloride with bis-[(R)-N-tert-butanesulfinyl]ethanediimine. There are two almost identical mol-ecules in the asymmetric unit, the mol-ecular conformation of which is stabilized by an intra-molecular N-H?N hydrogen bond.

| S-EPMC2959383 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data