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Organocatalysis in water at room temperature with in-flask catalyst recycling.

ABSTRACT: A new designer surfactant is described containing a covalently bound organocatalyst, proline. This species is water-soluble and, via spontaneous nanomicelle formation, catalyzes aldol reactions on water-soluble or -insoluble substrates in water as the only medium. Recycling the catalyst is trivial, as the amphiphile/catalyst remains in the aqueous phase in the flask.

SUBMITTER: Lipshutz BH 

PROVIDER: S-EPMC3359698 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

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Organocatalysis in water at room temperature with in-flask catalyst recycling.

Lipshutz Bruce H BH   Ghorai Subir S  

Organic letters 20111219 1

A new designer surfactant is described containing a covalently bound organocatalyst, proline. This species is water-soluble and, via spontaneous nanomicelle formation, catalyzes aldol reactions on water-soluble or -insoluble substrates in water as the only medium. Recycling the catalyst is trivial, as the amphiphile/catalyst remains in the aqueous phase in the flask. ...[more]

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