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[4,6-Dimethyl-pyrimidine-2(1H)-thione-?S]iodidobis(triphenyl-phosphane-?P)copper(I).

ABSTRACT: In the mononuclear title complex, [CuI(C(6)H(8)N(2)S)(C(18)H(15)P)(2)], the Cu(I) ion is in a slightly distorted tetra-hedral coordination geometry formed by two P atoms from two triphenyl-phosphane ligands, one S atom from a 4,6-dimethyl-pyrimidine-2(1H)-thione ligand and one iodide ion. There is an intra-molecular N-H?I hydrogen bond. In the crystal, ?-? stacking inter-actions [centroid-centroid distance = 3.594?(1)?Å] are observed.

SUBMITTER: Pakawatchai C

PROVIDER: S-EPMC3379106 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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[4,6-Dimethyl-pyrimidine-2(1H)-thione-κS]iodidobis(triphenyl-phosphane-κP)copper(I).

Pakawatchai Chaveng C Wattanakanjana Yupa Y Choto Patcharanan P Nimthong Ruthairat R

Acta crystallographica. Section E, Structure reports online 20120516 Pt 6

In the mononuclear title complex, [CuI(C(6)H(8)N(2)S)(C(18)H(15)P)(2)], the Cu(I) ion is in a slightly distorted tetra-hedral coordination geometry formed by two P atoms from two triphenyl-phosphane ligands, one S atom from a 4,6-dimethyl-pyrimidine-2(1H)-thione ligand and one iodide ion. There is an intra-molecular N-H⋯I hydrogen bond. In the crystal, π-π stacking inter-actions [centroid-centroid distance = 3.594 (1) Å] are observed. ...[more]

PMID: 22719327

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