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Iodido[5-methyl-1H-benzimidazole-2(3H)-thione-?S]bis-(triphenyl-phosphane-?P)copper(I) methanol monosolvate.

ABSTRACT: In the title compound, [CuI(C(8)H(8)N(2)S)(C(18)H(15)P)(2)]·CH(3)OH, the coordination environment around the Cu(I) atom is distorted tetra-hedral, defined by two P atoms of two triphenyl-phosphane ligands, one S atom of a 5-methyl-1H-benzimidazole-2(3H)-thione ligand and one I atom. The complex mol-ecules and the methanol solvent mol-ecules are connected via N-H?O and O-H?I hydrogen bonds, forming a chain along [010]. An intra-molecular N-H?I hydrogen bond is also observed.

SUBMITTER: Jiang YH

PROVIDER: S-EPMC3470167 | biostudies-literature | 2012 Oct

REPOSITORIES: biostudies-literature

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Iodido[5-methyl-1H-benzimidazole-2(3H)-thione-κS]bis-(triphenyl-phosphane-κP)copper(I) methanol monosolvate.

Jiang Yu-Han YH Qiu Qi-Ming QM Jiang Rui-Xia RX Huang Xu X Jin Qiong-Hua QH

Acta crystallographica. Section E, Structure reports online 20120926 Pt 10

In the title compound, [CuI(C(8)H(8)N(2)S)(C(18)H(15)P)(2)]·CH(3)OH, the coordination environment around the Cu(I) atom is distorted tetra-hedral, defined by two P atoms of two triphenyl-phosphane ligands, one S atom of a 5-methyl-1H-benzimidazole-2(3H)-thione ligand and one I atom. The complex mol-ecules and the methanol solvent mol-ecules are connected via N-H⋯O and O-H⋯I hydrogen bonds, forming a chain along [010]. An intra-molecular N-H⋯I hydrogen bond is also observed. ...[more]

PMID: 23125611

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