Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis[(diphenyl-phosphanylmeth-yl)diphenyl-phosphane sulfide-?(2)P,S]copper(I) hexa-fluoridophosphate.

ABSTRACT: In the title compound, [Cu(C(25)H(22)P(2)S)(2)]PF(6), the Cu(I) atom, lying on a twofold rotation axis, adopts a distorted tetra-hedral geometry. The (diphenyl-phosphanylmeth-yl)diphenyl-phos-phane sulfide ligand coordinates to the Cu(I) atom through one S and one P atom, forming a stable five-membered chelate ring. The P atom of the PF(6) (-) anion also lies on a twofold rotation axis.

SUBMITTER: Zhang JJ

PROVIDER: S-EPMC3379181 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Bis[(diphenyl-phosphanylmeth-yl)diphenyl-phosphane sulfide-κ(2)P,S]copper(I) hexa-fluoridophosphate.

Zhang Jing-Jing JJ Hu Feng F Duan Tai-Ke TK Chen Qun Q Zhang Qian-Feng QF

Acta crystallographica. Section E, Structure reports online 20120531 Pt 6

In the title compound, [Cu(C(25)H(22)P(2)S)(2)]PF(6), the Cu(I) atom, lying on a twofold rotation axis, adopts a distorted tetra-hedral geometry. The (diphenyl-phosphanylmeth-yl)diphenyl-phos-phane sulfide ligand coordinates to the Cu(I) atom through one S and one P atom, forming a stable five-membered chelate ring. The P atom of the PF(6) (-) anion also lies on a twofold rotation axis. ...[more]

PMID: 22719379

Similar Datasets

[1,1'-Bis(diphenyl-phosphan-yl)cobalto-cenium]carbonyl-chloridohydrido(triphenyl-phosphane)ruthenium(II) hexa-fluoridophosphate dichloro-methane disolvate.

Project description:In the title compound, [CoRu(C(17)H(14)P)(2)ClH(C(18)H(15)P)(CO)]PF(6)·2CH(2)Cl(2), the Ru(II) atom is coordinated by three P atoms from a chelating 1,1'-bis-(diphenyl-phosphan-yl)cobaltocenium ligand and a triphenyl-phosphine ligand, one CO ligand, one Cl atom and one H atom in a distorted octa-hedral geometry. In the cobaltocenium unit, the two cyclo-penta-dienyl rings are almost parallel, making a dihedral angle of 1.2?(3)°. The F atoms of the hexa-fluoridophosphate anion are disordered over two sets of sites, with an occupancy ratio of 0.849?(11):0.151?(11). Intra-molecular C-H?Cl hydrogen bonds occur in the complex cation. The complex cations, hexa-fluoridophosphate anions and dichloro-methane solvent mol-ecules are linked by inter-molecular C-H?F hydrogen bonds.

| S-EPMC3238603 | biostudies-literature

{Bis[2-(diphenyl-phosphino)eth-yl]phenyl-phosphine-?P,P',P''}chloridoplatinium(II) hexa-fluoridophosphate.

Project description:In the title compound, [PtCl(C(34)H(33)P(3))]PF(6), the Pt(II) cation adopts a distorted square-planar PtClP(3) geometry, arising from the P,P',P''-tridentate triphos ligand and a chloride ion. Four of the F atoms of the PF(6) (-) anion are disordered over two sets of positions in a 0.614?(17):0.386?(17) ratio.

| S-EPMC2969258 | biostudies-literature

{Bis[2-(diphenyl-phosphino)eth-yl]phenyl-phosphine-?P,P',P''}chloridopalladium(II) hexa-fluoridophosphate.

Project description:In the title compound, [PdCl(C(34)H(33)P(3))]PF(6), the Pd(II) atom adopts a distorted PdP(3)Cl square-planar geometry arising from the P,P',P''-tridentate triphos ligand and a chloride ion.

| S-EPMC2969369 | biostudies-literature

Bis[N,N-bis-(diphenyl-phosphan-yl)pentyl-amine-?P,P']platinum(II) bis-(hexa-fluoridophosphate) dichloro-methane disolvate.

Project description:The Pt(II) atom in the title compound, [Pt(C(29)H(31)NP(2))(2)](PF(6))(2)·2CH(2)Cl(2), is coordinated by four P atoms from two bis-(di-phenyl-phosphan-yl)pentyl-amine ligands with an average Pt-P distance of 2.300?(1)?Å. The coordination around the Pt(II) atom shows a highly distorted square-planar geometry, as evidenced by the P-Pt-P bite angles of 70.45?(3) and 70.64?(3)°. The asymmetric unit contains two hexa-fluoridophosphate ions, the metal complex and two dichloro-methane solvent mol-ecules. One of the chloride atoms of one of the dichloro-methane mol-ecules is disordered over two sites in a 0.515?(3):0.485?(3) ratio. C-H?F hydrogen bonds stabilize the crystal packing.

| S-EPMC3007544 | biostudies-literature

Chlorido[1-(diphenyl-phosphan-yl)cobaltocenium]gold(I) hexa-fluoridophosphate.

Project description:In the cobaltocenium group of the title compound, [AuCo(C(5)H(5))(C(17)H(14)P)Cl]PF(6), the substituted cyclo-penta-dienyl (Cps) and the unsubstituted cyclo-penta-dienyl (Cp) ring planes are almost parallel, making a dihedral angle of 3.1?(3)°. The C atoms in Cp and Cps are in an eclipsed conformation. The Au(I) atom is coordinated by a P atom from the diphenyl-phosphanyl group and a Cl atom in an almost linear arrangement [P-Au-Cl = 178.15-(7)°]. Two hexa-fluorido-phosphate anions are each located on a twofold rotation axis. In the crystal, the complex cations and hexa-fluorido-phosphate anions are linked via inter-molecular C-H?F hydrogen bonds.

| S-EPMC3120450 | biostudies-literature

Bis{1-[2-(diphenyl-phosphino)-ethyl]-3-ethylimidazol-2-yl-idene}palladium(II) bis-(hexa-fluoridophosphate) acetonitrile 2.85-solvate.

Project description:In the structure of the title compound, [Pd(C(19)H(21)N(2)P)(2)](PF(6))(2)·2.85CH(3)CN, the two six-membered NHC-phosphane chelate rings form a distorted square-planar coordination geometry around the Pd(II) atom, which lies 0.212?(1)?Å above the coordination plane. The sum of the bond angles at Pd(II) is 358.3°, with C-Pd-P bite angles of 84.03?(10) and 83.54?(9)°. The structure includes three acetonitrile solvent mol-ecules, one with partial site occupation and one with severe disorder, which was eventually excluded from the refinement.

| S-EPMC2979058 | biostudies-literature

(Di-tert-butyl-phosphan-yl)bis-(diphenyl-phosphan-yl)phosphane.

Project description:The title phosphane, C(32)H(38)P(4) or (Ph(2)P)(2)P(P(t)Bu(2)), has a P atom that is linked to another three P atoms in a pyramidal configuration; the P-P distances in the range 2.2231 (7)-2.2446 (7) Å indicate that the P-P bonds are single bonds.

| S-EPMC2961699 | biostudies-literature

Bis{1,4-bis-[(3-butyl-imidazolium-1-yl)meth-yl]benzene}-silver(I) bis-(hexa-fluoridophosphate).

Project description:The asymmetric unit of the title complex, [Ag(2)(C(22)H(30)N(4))(2)](PF(6))(2), consists of one Ag(I) ion, one 1,4-bis-[(3-butyl-imidazolium-1-yl)meth-yl]benzene ligand and one discrete hexa-fluoridophosphate anion. The formula unit is generated by an inversion center. The unique Ag(I) ion is coordinated by two C atoms of two heterocyclic carbene ligands in an essentially linear geometry. In the crystal structure, cations and anions are linked through weak C-H⋯F hydrogen bonds, forming a three-dimensional network.

| S-EPMC2983204 | biostudies-literature

(2-Amino-ethane-thiol-ato-?(2)N,S)bis-[1,2-bis-(diphenyl-phosphan-yl)ethane-?(2)P,P']ruthenium(II) hexa-fluoridophosphate.

Project description:In the crystal of the title compound, [Ru(C(2)H(6)NS)(C(26)H(24)P(2))(2)]PF(6), the Ru(II) atom is in a slightly distorted octa-hedral geometry, coordinated by one 2-amino-ethane-thiol-ate (aet) and two 1,2-bis-(diphenyl-phosphan-yl)ethane (dppe) ligands. The crystal consists of a pair of enanti-omers (? and ?) of the compound. The ? and ? isomers have the ? and ? conformations for the aet chelate rings and the ? and ? conformations for the dppe chelate rings. The F atoms of the PF(6) (-) counter-anion are disordered over three positions, with site occupancies of 0.4, 0.3 and 0.3.

| S-EPMC3515165 | biostudies-literature

9,10-Bis{2-[1-(2-pyridylmeth-yl)imidazolium-3-yl]eth-oxy}anthracene bis(hexa-fluoridophosphate).

Project description:The cation of the title compound, C(36)H(34)N(6)O(2) (2+)·2PF(6) (-), lies across a crystallographic inversion centre. The imidazole and pyridine rings form dihedral angles of 82.28 (5)° and 11.87 (7)°, respectively, with the anthracene ring system. The crystal packing is stabilized by π-π inter-actions between the pyridine ring and the central ring of anthracene, with a ring centroid-centroid distance of 3.684 (3) Å. The PF(6) (-) anion is disordered over three different positions with occupancies of 0.284 (6), 0.354 (8) and 0.362 (9).

| S-EPMC2915252 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data