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Bis[(diphenyl-phosphanylmeth-yl)diphenyl-phosphane sulfide-?(2)P,S]copper(I) hexa-fluoridophosphate.

ABSTRACT: In the title compound, [Cu(C(25)H(22)P(2)S)(2)]PF(6), the Cu(I) atom, lying on a twofold rotation axis, adopts a distorted tetra-hedral geometry. The (diphenyl-phosphanylmeth-yl)diphenyl-phos-phane sulfide ligand coordinates to the Cu(I) atom through one S and one P atom, forming a stable five-membered chelate ring. The P atom of the PF(6) (-) anion also lies on a twofold rotation axis.

SUBMITTER: Zhang JJ

PROVIDER: S-EPMC3379181 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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Bis[(diphenyl-phosphanylmeth-yl)diphenyl-phosphane sulfide-κ(2)P,S]copper(I) hexa-fluoridophosphate.

Zhang Jing-Jing JJ Hu Feng F Duan Tai-Ke TK Chen Qun Q Zhang Qian-Feng QF

Acta crystallographica. Section E, Structure reports online 20120531 Pt 6

In the title compound, [Cu(C(25)H(22)P(2)S)(2)]PF(6), the Cu(I) atom, lying on a twofold rotation axis, adopts a distorted tetra-hedral geometry. The (diphenyl-phosphanylmeth-yl)diphenyl-phos-phane sulfide ligand coordinates to the Cu(I) atom through one S and one P atom, forming a stable five-membered chelate ring. The P atom of the PF(6) (-) anion also lies on a twofold rotation axis. ...[more]

PMID: 22719379

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