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[6-(4-Bromo-phen-yl)-2,2'-bipyridine-?N,N']bis-(triphenyl-phosphane-?P)copper(I) tetra-fluoridoborate.

ABSTRACT: The title compound, [Cu(C(16)H(11)BrN(2))(C(18)H(15)P)(2)]BF(4), is composed of one Cu(I) atom, one 6-(4-bromo-phen-yl)-2,2'-bipyridine (L) ligand, two triphenyl-phosphane mol-ecules and one tetra-fluoridoborate anion. The Cu(I) ion is four-coordinated in a distorted tetra-hedral configuration by two N atoms from L and two P atoms from triphenyl-phosphane ligands. In the L ligand, the two pyridine rings are not coplanar; the mean planes making a dihedral angle of 15.3?(5)°. In the crystal, the ions are linked by weak C-H?F inter-actions.

SUBMITTER: Lin YR

PROVIDER: S-EPMC3200642 | biostudies-literature | 2011 Sep

REPOSITORIES: biostudies-literature

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[6-(4-Bromo-phen-yl)-2,2'-bipyridine-κN,N']bis-(triphenyl-phosphane-κP)copper(I) tetra-fluoridoborate.

Lin Yan-Ru YR Huang Jun-Sheng JS Zhong Ming-Hua MH

Acta crystallographica. Section E, Structure reports online 20110802 Pt 9

The title compound, [Cu(C(16)H(11)BrN(2))(C(18)H(15)P)(2)]BF(4), is composed of one Cu(I) atom, one 6-(4-bromo-phen-yl)-2,2'-bipyridine (L) ligand, two triphenyl-phosphane mol-ecules and one tetra-fluoridoborate anion. The Cu(I) ion is four-coordinated in a distorted tetra-hedral configuration by two N atoms from L and two P atoms from triphenyl-phosphane ligands. In the L ligand, the two pyridine rings are not coplanar; the mean planes making a dihedral angle of 15.3 (5)°. In the crystal, the i ...[more]

PMID: 22058839

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