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Diiodido{2-[(4-meth-oxy-phen-yl)imino-meth-yl]pyridine-?(2)N,N'}zinc.

ABSTRACT: In the title complex, [ZnI(2)(C(13)H(12)N(2)O)], the Zn(II) atom has a distorted tetra-hedral coordination. The organic ligand is bidentate, coordinating the Zn(II) atom via the two N atoms. The benzene and pyridine rings are oriented at a dihedral angle of 11.67?(9)°. In the crystal, weak C-H?I and C-H?O hydrogen bonds are observed, in addition to ?-? stacking inter-actions, with a centroid-centroid distance of 3.72?(5)?Å.

SUBMITTER: Salehzadeh S

PROVIDER: S-EPMC3414111 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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Diiodido{2-[(4-meth-oxy-phen-yl)imino-meth-yl]pyridine-κ(2)N,N'}zinc.

Salehzadeh Sadegh S Khalaj Mehdi M Dehghanpour Saeed S

Acta crystallographica. Section E, Structure reports online 20120710 Pt 8

In the title complex, [ZnI(2)(C(13)H(12)N(2)O)], the Zn(II) atom has a distorted tetra-hedral coordination. The organic ligand is bidentate, coordinating the Zn(II) atom via the two N atoms. The benzene and pyridine rings are oriented at a dihedral angle of 11.67 (9)°. In the crystal, weak C-H⋯I and C-H⋯O hydrogen bonds are observed, in addition to π-π stacking inter-actions, with a centroid-centroid distance of 3.72 (5) Å. ...[more]

PMID: 22904718

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