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Dichlorido(1-{(E)-[phen-yl(pyridin-2-yl-?N)methyl-idene]amino-?N}pyrrolidin-2-one-?O)copper(II) monohydrate.

ABSTRACT: The Cu(II) atom in the title compound, [CuCl(2)(C(16)H(15)N(3)O)]·H(2)O, is N,N',O-chelated by the neutral Schiff base ligand and exists in a square-pyramidal geometry. It is displaced by 0.316?(1)?Å out of the square plane (r.m.s. deviation = 0.015?Å) in the direction of the apical Cl atom. The apical Cl atoms of adjacent complex units are hydrogen-bond acceptors to two water mol-ecules, the inter-action generating a centrosymmetric dimer through a cyclic R(4) (2)(8) association.

SUBMITTER: Kunnath RJ

PROVIDER: S-EPMC3435603 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

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Dichlorido(1-{(E)-[phen-yl(pyridin-2-yl-κN)methyl-idene]amino-κN}pyrrolidin-2-one-κO)copper(II) monohydrate.

Kunnath Roji J RJ Prathapachandra Kurup M R MR Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20120823 Pt 9

The Cu(II) atom in the title compound, [CuCl(2)(C(16)H(15)N(3)O)]·H(2)O, is N,N',O-chelated by the neutral Schiff base ligand and exists in a square-pyramidal geometry. It is displaced by 0.316 (1) Å out of the square plane (r.m.s. deviation = 0.015 Å) in the direction of the apical Cl atom. The apical Cl atoms of adjacent complex units are hydrogen-bond acceptors to two water mol-ecules, the inter-action generating a centrosymmetric dimer through a cyclic R(4) (2)(8) association. ...[more]

PMID: 22969476

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