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Trichlorido(dimethyl sulfoxide-?O)(di-2-pyridyl-amine-?(2)N,N')indium(III).

ABSTRACT: In the title compound, [InCl(3)(C(10)H(9)N(3))(C(2)H(6)OS)], the In(III) atom is six-coordinated in a distorted octa-hedral geometry by two N atoms from a chelating di-2-pyridyl-amine ligand, one O atom from a dimethyl sulfoxide ligand and three Cl atoms. Inter-molecular C-H?Cl hydrogen bonds and ?-? contacts between the pyridine rings [centroid-centroid distance = 3.510?(3)?Å] are present in the crystal.

SUBMITTER: Shirvan SA

PROVIDER: S-EPMC3470143 | biostudies-literature | 2012 Oct

REPOSITORIES: biostudies-literature

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Trichlorido(dimethyl sulfoxide-κO)(di-2-pyridyl-amine-κ(2)N,N')indium(III).

Shirvan Sadif A SA Haydari Dezfuli Sara S Golabi Elyas E

Acta crystallographica. Section E, Structure reports online 20120912 Pt 10

In the title compound, [InCl(3)(C(10)H(9)N(3))(C(2)H(6)OS)], the In(III) atom is six-coordinated in a distorted octa-hedral geometry by two N atoms from a chelating di-2-pyridyl-amine ligand, one O atom from a dimethyl sulfoxide ligand and three Cl atoms. Inter-molecular C-H⋯Cl hydrogen bonds and π-π contacts between the pyridine rings [centroid-centroid distance = 3.510 (3) Å] are present in the crystal. ...[more]

PMID: 23125587

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